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Merck
CN

47794

1,2,3-三氯丙烷

analytical standard

别名:

Trichlorohydrin, 三氯丙烷

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关于此项目

线性分子式:
CH2ClCHClCH2Cl
化学文摘社编号:
96-18-4
分子量:
147.43
EC Number:
202-486-1
UNSPSC Code:
12352200
PubChem Substance ID:
24871430
Beilstein/REAXYS Number:
1732068
MDL number:
MFCD00000946
NACRES:
NA.24

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InChI key

CFXQEHVMCRXUSD-UHFFFAOYSA-N

InChI

1S/C3H5Cl3/c4-1-3(6)2-5/h3H,1-2H2

SMILES string

ClCC(Cl)CCl

grade

analytical standard

CofA

current certificate can be downloaded

packaging

ampule of 1000 mg

technique(s)

HPLC: suitable, gas chromatography (GC): suitable

Quality Level

100

bp

156 °C (lit.)

mp

−14 °C (lit.)

density

1.387 g/mL at 25 °C (lit.)

application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

storage temp.

2-30°C

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相关类别

General description

This compound is listed in the SVHC (Substances of very high concern) candidate list of ECHA (European Chemicals Agency)

Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

pictograms

Skull and crossbonesHealth hazard
GHS06,GHS08

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Chronic 3 - Carc. 1B - Eye Irrit. 2 - Muta. 2 - Repr. 1B - STOT RE 1 Inhalation

target_organs

Kidney,Liver,Mucous membranes

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

flash_point_f

165.2 °F - DIN 51758

flash_point_c

74 °C - DIN 51758

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
LRAE0829
LRAD2863
LRAD7635
LRAC5862
LC25649V

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Martina Pavlova et al.
Nature chemical biology, 5(10), 727-733 (2009-08-25)
Engineering enzymes to degrade anthropogenic compounds efficiently is challenging. We obtained Rhodococcus rhodochrous haloalkane dehalogenase mutants with up to 32-fold higher activity than wild type toward the toxic, recalcitrant anthropogenic compound 1,2,3-trichloropropane (TCP) using a new strategy. We identified key
Marta Monincová et al.
Applied and environmental microbiology, 73(6), 2005-2008 (2007-01-30)
1,2,3-Trichloropropane (TCP) is a highly toxic and recalcitrant compound. Haloalkane dehalogenases are bacterial enzymes that catalyze the cleavage of a carbon-halogen bond in a wide range of organic halogenated compounds. Haloalkane dehalogenase LinB from Sphingobium japonicum UT26 has, for a
Pavel Banás et al.
Journal of computer-aided molecular design, 20(6), 375-383 (2006-10-04)
1,2,3-Trichloropropane (TCP) is a highly toxic, recalcitrant byproduct of epichlorohydrin manufacture. Haloalkane dehalogenase (DhaA) from Rhodococcus sp. hydrolyses the carbon-halogen bond in various halogenated compounds including TCP, but with low efficiency (k (cat)/K (m )= 36 s(-1) M(-1)). A Cys176Tyr-DhaA
Alena Stsiapanava et al.
Acta crystallographica. Section F, Structural biology and crystallization communications, 67(Pt 2), 253-257 (2011-02-09)
Haloalkane dehalogenases make up an important class of hydrolytic enzymes which catalyse the cleavage of carbon-halogen bonds in halogenated aliphatic compounds. There is growing interest in these enzymes owing to their potential use in environmental and industrial applications. The haloalkane
Alexandra J Salter-Blanc et al.
Environmental science & technology, 45(9), 4073-4079 (2011-04-14)
The reactivity of zerovalent zinc (ZVZ) toward 1,2,3-trichloropropane (TCP) was evaluated under a variety of solution conditions, including deionized water, groundwater, and artificial groundwater, over a pH range of about 6.5-12. In deionized water, first-order rate constants for TCP disappearance
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