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Merck
CN

48492

苯并[k]荧蒽

analytical standard

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关于此项目

经验公式（希尔记法）:
C20H12
化学文摘社编号:
207-08-9
分子量:
252.31
EC Number:
205-916-6
UNSPSC Code:
23151816
PubChem Substance ID:
24872001
Beilstein/REAXYS Number:
1873745
MDL number:
MFCD00046287

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产品名称

苯并[k]荧蒽, analytical standard

InChI key

HAXBIWFMXWRORI-UHFFFAOYSA-N

InChI

1S/C20H12/c1-2-6-15-12-19-17-10-4-8-13-7-3-9-16(20(13)17)18(19)11-14(15)5-1/h1-12H

SMILES string

c1ccc2cc-3c(cc2c1)-c4cccc5cccc-3c45

grade

analytical standard

packaging

ampule of 50 mg

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

mp

215-217 °C (lit.)

solubility

95% ethanol: <1 mg/mL at 20 °C
DMSO: <1 mg/mL at 20 °C
H2O: <1 mg/mL at 20 °C
acetone: 1-10 mg/mL at 20 °C
methanol: <1 mg/mL at 20 °C
toluene: 5-10 mg/mL at 20 °C

application(s)

cleaning products
cosmetics
environmental
food and beverages
personal care

format

neat

storage temp.

2-8°C

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Application

Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

General description

Benzo[k]fluoranthene belongs to the class of polycyclic aromatic hydrocarbons. It can find applications as a chemical sensor for nitrated aromatic compounds via fluorescence quenching of benzo[k]fluoranthene in poly(vinyl alcohol) film. It can also serve as a potential candidate in organic light emitting diodes.
This compound is listed in the SVHC (Substances of very high concern) candidate list of ECHA (European Chemicals Agency)

pictograms

Health hazardEnvironment
GHS08,GHS09

signalword

Danger

hcodes

H350,H410

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B

存储类别

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk

WGK 3

ppe

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
LC25169V
LC23841V
LC18307V
LC10008V
LB92853V

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Fluorescence quenching of benzo [k] fluoranthene in poly (vinyl alcohol) film: a possible optical sensor for nitro aromatic compounds
Patra D and Mishra.K.A
Sensors and Actuators B, Chemical, 80, 278-282 (2001)
Optical absorption and emission properties of fluoranthene, benzo [k] fluoranthene, and their derivatives. A DFT study
Saranya.G, et al.
The Journal of Physical Chemistry A, 115, 14647-14656 (2011)
Tohru Saitoh et al.
Talanta, 79(2), 177-182 (2009-06-30)
A simple and rapid method for the highly sensitive determination of polycyclic aromatic hydrocarbons (PAHs) in water was developed. Benzo[a]pyrene, benzo[k]fluoranthene, perylene, and pyrene in water were concentrated into sodium dodecyl sulfate (SDS)-alumina admicelles. The collection was performed by adding
Erin E Bessette et al.
Drug metabolism and disposition: the biological fate of chemicals, 33(3), 312-320 (2004-12-04)
Polycyclic aromatic hydrocarbons (PAHs) and heavy metals are often environmental cocontaminants that could interact to alter PAH carcinogenicity. The heavy metal, arsenite, and the PAH, benzo[k]fluoranthene, were used as prototypes to investigate, in human HepG2 cells, mechanisms whereby the bioactivation
G Verrhiest et al.
Ecotoxicology (London, England), 10(6), 363-372 (2002-01-05)
Polycyclic Aromatic Hydrocarbons (PAHs) are ubiquitous pollutants of sediments. Sediment quality criteria often use toxicity data for individual PAHs. However, PAHs always occur in field sediments as a complex mixture of compounds. In this study, the toxicity of phenanthrene (P)
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