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Merck
CN

CRM68173

去乙基阿特拉津

certified reference material, TraceCERT®, Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

别名:

2-氨基-4-氯-6-异丙氨基-1,3,5-三嗪, 去乙基莠去津

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关于此项目

经验公式(希尔记法):
C6H10ClN5
化学文摘社编号:
分子量:
187.63
NACRES:
NA.24
UNSPSC Code:
41116107
Beilstein/REAXYS Number:
610488
MDL number:
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Quality Level

product line

TraceCERT®

grade

certified reference material, TraceCERT®

shelf life

limited shelf life, expiry date on the label

manufacturer/tradename

Manufactured by: Sigma-Aldrich Production GmbH, Switzerland

SMILES string

CC(C)Nc1nc(N)nc(Cl)n1

InChI

1S/C6H10ClN5/c1-3(2)9-6-11-4(7)10-5(8)12-6/h3H,1-2H3,(H3,8,9,10,11,12)

InChI key

DFWFIQKMSFGDCQ-UHFFFAOYSA-N

General description

This certified reference material (CRM) is produced and certified in accordance with ISO/IEC 17025 and ISO 17034. This CRM is traceable to primary material from an NMI, e.g. NIST or NMIJ.
Certified content by quantitative NMR incl. uncertainty and expiry date are given on the certificate.
Download your certificate at: http://www.sigma-aldrich.com
Atrazine-desethyl is a major cytochrome P450s (CYPs) derived metabolite of the herbicide atrazine, widely used for protection against broadleaf and grassy weeds in various crops. It has more stability than its parent atrazine and the same endocrine-disrupting toxicity.
The parent compound atrazine is not approved for use in the European Union (EU) as per the legislation 2004/248/EC of 24th March 2004. But atrazine has a maximum residue limit (MRL) set in the range of 0.01-2 mg/kg for its presence in soybean, corn, and wheat crops by the United States (US) and the European Union (EU).

Application

The certified reference material (CRM) is intended to be used as a calibrant for chromatography and other analytical techniques.
The atrazine-desethyl CRM may also find below-given uses:

  • Analysis of atrazine and its major metabolites in water and soil samples by using multi-walled carbon nanotubes for solid-phase extraction (SPE) and gas chromatography-mass spectrometry (GC-MS) for detection
  • QuEChERS-based extraction and liquid chromatography-diode-array detection (LC-DAD) of atrazine and its principal metabolites in natural water samples
  • Development of a carboxyl-modified polyacrylonitrile nanofibers mat (COOH-PAN NFsM) for the solid phase extraction (SPE) of atrazine and its metabolites from environmental water samples followed by their determination using high-performance liquid chromatography-diode array detector (HPLC-DAD)
  • Analysis of simazine and atrazine extracted from river water by reversed-phase liquid chromatography with ultraviolet detection (LC-UV)
  • Simultaneous separation and determination of atrazine and its main metabolites in 15 samples each of soybean, corn, and wheat by a novel UPLC-ESI-MS/MS-based method

Legal Information

TraceCERT is a registered trademark of Merck KGaA, Darmstadt, Germany


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signalword

Warning

Hazard Classifications

Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Irrit. 2

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable



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Determination of simazine and atrazine in river water by cloud-point extraction and high-performance liquid chromatography
de Pra Urio R and Masini J C
Analytical Letters, 50(7) (2017)
Guang Min et al.
The Science of the total environment, 396(1), 79-85 (2008-03-29)
A novel, simple, cost-effective, and sensitive method was developed for the determination of atrazine and its principal metabolites namely deisopropyl-atrazine (DIA) and deethyl-atrazine (DEA) in water and soil samples using multi-walled carbon nanotubes as solid-phase extraction (SPE) adsorbents coupled with
Analysis of herbicide atrazine and its degradation products in cereals by ultra-performance liquid chromatography-mass spectrometry
Liang S, et al.
Analytical Methods : Advancing Methods and Applications, 8(17) (2016)



全球贸易项目编号

货号GTIN
CRM68173-100MG04065265038423