126179

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A synthetic precedent for the [FeIV2(mu-O)2] diamond core proposed for methane monooxygenase intermediate Q.

Genqiang Xue et al.

Proceedings of the National Academy of Sciences of the United States of America, 104(52), 20713-20718 (2007-12-21)

Intermediate Q, the methane-oxidizing species of soluble methane monooxygenase, is proposed to have an [Fe(IV)(2)(mu-O)(2)] diamond core. In an effort to obtain a synthetic precedent for such a core, bulk electrolysis at 900 mV (versus Fc(+/0)) has been performed in

Reactivity of bio-inspired Cu(II) (N2/Py2) complexes with peroxide at room temperature.

Nirupama Singh et al.

Journal of inorganic biochemistry, 197, 110674-110674 (2019-05-21)

Developing coordination complexes of earth abundant metals that can perform substrate oxidations under benign conditions is an ongoing challenge. Herein, the reactivity of two mononuclear Cu-complexes toward the oxidant H2O2 is reported. Both complexes displayed ligand oxidation upon reaction with

Mechanistic insights into the reactions of hydride transfer versus hydrogen atom transfer by a trans-dioxoruthenium(VI) complex.

Sunder N Dhuri et al.

Dalton transactions (Cambridge, England : 2003), 44(16), 7634-7642 (2015-03-27)

A mononuclear high-valent trans-dioxoruthenium(VI) complex, trans-[Ru(VI)(TMC)(O)2](2+) (TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane), was synthesized and characterized by various spectroscopic techniques and X-ray crystallography. The reactivity of the trans-[Ru(VI)(TMC)(O)2](2+) complex was investigated in hydride transfer and hydrogen atom transfer reactions. The mechanism of hydride

A Lithium-Organic Primary Battery.

Pengfei Sun et al.

Small (Weinheim an der Bergstrasse, Germany), 16(3), e1906462-e1906462 (2019-12-24)

Lithium primary batteries are still widely used in military, aerospace, medical, and civilian applications despite the omnipresence of rechargeable Li-ion batteries. However, these current primary chemistries are exclusively based on inorganic materials with high cost, low energy density or severe

Retention modeling and retention time prediction in gas chromatography and flow-modulation comprehensive two-dimensional gas chromatography: The contribution of pressure on solute partition.

Antoine Burel et al.

Journal of chromatography. A, 1485, 101-119 (2017-01-22)

This study aims at modelling and predicting solute retention in capillary Gas Chromatography (GC) and Flow Modulation comprehensive GC (FM-GCxGC). A new thermodynamic model, taking into account the effects of temperature and pressure, is proposed to describe the variation of

[7H] Benzanthrone, a catalyst for the transfer hydrogenation of C₆₀and C₇₀by 9, 10-dihydroanthracene.

Gerst M, et al.

Tetrahedron Letters, 34(48), 7729-7732 (1993)

Oxidative aromatization of 9,10-dihydroanthracenes using molecular oxygen promoted by activated carbon.

Natsuki Nakamichi et al.

The Journal of organic chemistry, 68(21), 8272-8273 (2003-10-11)

Substituted 9,10-dihydroanthracenes were oxidatively aromatized to the corresponding anthracenes effectively by using molecular oxygen as an oxidant and activated carbon (Darco KB, Aldrich, Inc.) as a promoter in xylene.

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