Merck
CN
Search Within

243086

应用筛选条件
关键词:'243086'
显示 1-30 共 44 条结果 关于 "243086" 范围 论文
Nathalie Ségaud et al.
Inorganic chemistry, 52(2), 691-700 (2013-01-11)
We report the synthesis, characterization, and solution chemistry of a series of new Fe(II) complexes based on the tetradentate ligand N-methyl-N,N'-bis(2-pyridyl-methyl)-1,2-diaminoethane or the pentadentate ones N,N',N'-tris(2-pyridyl-methyl)-1,2-diaminoethane and N,N',N'-tris(2-pyridyl-methyl)-1,3-diaminopropane, modified by propynyl or methoxyphenyltriazolyl groups on the amino functions. Six of
Jin Wang et al.
Journal of nanoscience and nanotechnology, 13(1), 523-528 (2013-05-08)
The low bandgap 3-hexylthiophene/pyridine copolymers (P3HT/PY) were synthesized and the composites of P3HT/PY and CdSe QDs were prepared. The characterization are performed with 1H NMR, UV-vis, PL, TEM, XPS and cyclic voltammetry (CV). The results show that the P3HT/PY copolymers
Hani Nasser Abdelhamid et al.
Analytica chimica acta, 767, 104-111 (2013-03-05)
Application of two new series of ionic liquid matrices (ILMs) based on the two most predominantly used conventional organic matrices (Sinapinic acid and 2,5-DHB) in conjugation with various bases (aniline (ANI), dimethyl aniline (DMANI), diethylamine (DEA), dicyclohexylamine (DCHA), pyridine (Pyr)
V Divya et al.
Dalton transactions (Cambridge, England : 2003), 42(34), 12317-12323 (2013-07-16)
Our recently developed Eu(3+) coordination compound, Eu(pfppd)3(tpy) [where Hpfppd = 4,4,5,5,5-pentafluoro-3-hydroxy-1-(phenanthren-3-yl)pentanedione and tpy = 2,2':6,6''-terpyridine] exhibits significant quantum yield (Φoverall = 41%) and long (5)D0 lifetime (880 μs) values under biologically relevant pH conditions (pH = 7.4) when excited with
Jipan Yu et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(13), 4271-4277 (2013-02-13)
Efficient copper-catalyzed aerobic oxidative C-H and C-C functionalization of 1-[2-(arylamino)aryl]ethanones leading to acridones has been developed. The procedure involves cleavage of aromatic C-H and acetyl C-C bonds with intramolecular formation of a diarylketone bond. The protocol uses inexpensive Cu(O2CCF3)2 as
Fei Tian et al.
Journal of environmental sciences (China), 25(11), 2299-2305 (2014-02-21)
A series of precious metals catalysts (M/TiO2, M = Ru, Rh, Pd, Ag, Ir, Pt or Au) were prepared by a light deposition method and the synergistic photocatalytic degradations of pyridine (20 mg/L) under UV irradiation (365 nm) using M/TiO2
V Subbaramaiah et al.
Journal of hazardous materials, 248-249, 355-363 (2013-02-19)
Cerium supported SBA-15 (Ce/SBA-15) was synthesized by two-step synthesis method in acidic medium. It was further characterized by various characterization techniques such as X-ray diffraction, field-emission scanning electron microscopy, Fourier transform infrared spectroscopy and N2 adsorption-desorption pore size distribution analysis.
Jacky Pouessel et al.
Dalton transactions (Cambridge, England : 2003), 42(14), 4859-4872 (2013-02-02)
The synthesis of a new linear bis-tetraamine ligand L1, based on two 1,4,8,11-tetraazaundecane units grafted at the 2 and 6 positions of a pyridinyl linker substituted by an anthracenyl fluorophore in the para position, is described and anion complexation studies
Yuya Kodama et al.
Journal of medicinal chemistry, 56(22), 9342-9350 (2013-11-01)
In this study, we developed an assignment-free approach for rapid identification of ligand-binding sites in target proteins by using NMR. With a sophisticated cell-free stable isotope-labeling procedure that introduces (15)N- or (13)C-labels to specific atoms of target proteins, this approach
Harry Adams et al.
Journal of the American Chemical Society, 135(5), 1853-1863 (2013-01-31)
The association constants for a family of 96 closely related zinc porphyrin-pyridine ligand complexes have been measured in two different solvents, toluene and 1,1,2,2-tetrachloroethane (TCE). The zinc porphyrin receptors are equipped with phenol side arms, which can form intramolecular H-bonds
José M M Lima et al.
Journal of molecular modeling, 19(4), 1727-1737 (2013-01-09)
Nitric oxide (NO) is an important chemical compound involved in many physiological and pathological processes in living organisms. However, nitric oxide is a very reactive radical that needs to be carried through organisms to reach the desired biological target. With
So-Young Ma et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 113, 261-267 (2013-06-06)
The solid-state structures and unequivocal stereochemistries of isomeric pyridine-based leuco-triarylmethane (LTAM) dyes 2,2'-(2-(pyridin-4 or 3-yl)propane-1,3-diylidene)bis(5-chloro-1,3,3-trimethylindoline) derivatives were established by X-ray crystallography. Surprisingly, the EE isomer was formed for the 4-pyridinyl compound, whereas the 3-pyridinyl compound formed ZE isomers. In addition
Junichi Hoshino et al.
Journal of nanoscience and nanotechnology, 13(7), 4593-4600 (2013-08-02)
Thymidine derivatives with carboxylic acid and pyridyl groups were synthesized for constructing one-dimensional network structure based on hydrogen bonding in crystalline state. The solid sate structures and hydrogen bonding networks of the thymidine derivatives were characterized by single X-ray diffraction
Nicolas Zydziak et al.
Macromolecular rapid communications, 34(8), 672-680 (2013-03-19)
Single-walled carbon nanotubes (SWCNTs) are pre-functionalized with a pyridinyl-based dithioester to undergo a hetero Diels-Alder (HDA) reaction with cyclopentadienyl end-capped poly(methyl)methacrylate (Mn = 2700 g mol(-1) , PDI = 1.14). Fourier transform infrared spectroscopy, thermogravimetric analysis, elemental analysis (EA), and
C-demethylation and methyl group migration during O-demethylation with pyridine hydrochloride
JHP and T
Journal of the Chemical Society. Chemical Communications, 914-915 (1972)
Daniel Sieh et al.
Journal of the American Chemical Society, 135(10), 3971-3982 (2013-02-26)
Si-H activation in triethyl- and triarylsilanes by a square-planar pyridine-diimine iridium complex with a terminal nitrido unit leads to the corresponding silyl amido complexes, which were unambiguously characterized by X-ray crystallography. Based on detailed combined kinetic and theoretical studies (DFT)
Kalina Szteyn et al.
Pain, 156(11), 2364-2372 (2015-07-15)
Glutamate serves as the primary excitatory neurotransmitter in the nervous system. Previous studies have identified a role for glutamate and group I metabotropic receptors as targets for study in peripheral inflammatory pain. However, the coordination of signaling events that transpire
Ye Wei et al.
Journal of the American Chemical Society, 135(10), 3756-3759 (2013-02-27)
We describe here a [3+3]-type condensation reaction of O-acetyl ketoximes and α,β-unsaturated aldehydes that is synergistically catalyzed by a copper(I) salt and a secondary ammonium salt (or amine). This redox-neutral reaction allows modular synthesis of a variety of substituted pyridines
Prasanta Das et al.
The Journal of chemical physics, 138(5), 054307-054307 (2013-02-15)
With infrared absorption spectra we investigated the reaction between Cl atom and pyridine (C(5)H(5)N) in a para-hydrogen (p-H(2)) matrix. Pyridine and Cl(2) were co-deposited with p-H(2) at 3.2 K; a planar C(5)H(5)N-Cl(2) complex was identified from the observed infrared spectrum
Tatyana N Sevastyanova et al.
Molecular pharmacology, 86(5), 492-504 (2014-08-13)
Metabotropic glutamate receptors (mGluRs) function as dimers. Recent work suggests that mGluR1 and mGluR5 may physically interact, but the nature and functional consequences of this relationship have not been addressed. In this study, the functional and pharmacological consequences of this
Karen D M MaGee et al.
Dalton transactions (Cambridge, England : 2003), 42(12), 4233-4236 (2013-02-13)
The coordination of 2-pyridyltetrazolate and ortho-xylene-linked bis(NHC)cyclophane to Pt(II) yielded a novel complex characterised by enhanced pure deep-blue emission, whose intensity can be modulated via methylation of the tetrazole ring.
Ritambhara Sharma et al.
Dalton transactions (Cambridge, England : 2003), 42(16), 5627-5630 (2013-03-20)
Our successful synthesis of the first examples of Sn(IV) complexes of meso-aryl dipyrrins is reported. Sn(IV) dipyrrins are synthesized by treating meso-aryl dipyrrins with readily available SnCl2·2H2O in pyridine at reflux temperature and isolated as pure complexes by recrystallization. The
Vandana Bhalla et al.
Dalton transactions (Cambridge, England : 2003), 42(13), 4450-4455 (2013-01-26)
Nanoaggregates of a supramolecular ensemble of triphenylene derivative 3 and Cu(2+) ions exhibit 'turn-on' response towards CN(-) ions in an aqueous medium and can detect the trace amount of inorganic cyanide ions (NaCN) in tap water and blood serum milieu.
Marcin Mielecki et al.
Biochimica et biophysica acta, 1834(7), 1292-1301 (2013-03-26)
The RIO kinases are essential protein factors required for the synthesis of new ribosomes in eukaryotes. Conserved in archaeal organisms as well, RIO kinases are among the most ancient of protein kinases. Their exact molecular mechanisms are under investigation and
Hidenori Otsuka et al.
Journal of nanoscience and nanotechnology, 13(1), 537-544 (2013-05-08)
The novel amphiphilic comb-type copolymers were synthesized by copolymerization of a unit A that contains a pyridine (Py) portion and a unit B that contains a poly(ethylene glycol) (PEG) portion. The obtained copolymers consist of methoxy-endend PEG as a hydrophiphilic
James B Gerken et al.
Inorganic chemistry, 52(6), 2796-2798 (2013-03-06)
A modular synthetic method has been developed for the preparation of Ru polypyridyl complexes bearing a terminal alkyne. This method proceeds through a readily accessible intermediate with a silyl-protected alkyne and allows access to a variety of five- and six-coordinate
Zipping and unzipping of a paddlewheel metal-organic framework to enable two-step synthetic and structural transformation.
Paul Smart et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 19(11), 3552-3557 (2013-02-13)
Bidyut Akhuli et al.
Dalton transactions (Cambridge, England : 2003), 42(16), 5818-5825 (2013-03-05)
A pentafluorophenyl (–C6F5) substituted 3-pyridyl urea, L(1), is explored extensively to demonstrate SO4(2-) binding exclusively via second sphere coordination in the cavity of a 1D polymeric self-assembly of L(1), selectively assisted by Cu2+. A single crystal X-ray diffraction study depicts
Liqun Shen et al.
Molecules (Basel, Switzerland), 18(2), 1602-1612 (2013-01-29)
A new pyridine-pyrazole N-N ligand has been conveniently synthesized and characterized by ¹H-, ¹³C-NMR, IR spectroscopies, HRMS and X-ray single-crystal crystallography analyses. The ligand adds to palladium(II) under basic conditions to give high yields of an air-stable and water-soluble complex
Lotfali Saghatforoush et al.
Acta chimica Slovenica, 60(2), 300-309 (2013-07-25)
Two new Cd(II) complexes, with the ligand 4'-(4-chlorophenyl)-2,2':6',2"-terpyridine (Clphtpy) formulated as: [Cd(Clphtpy)(NO3)2H2O] (1), and [Cd(Clphtpy)(N3)2]2 (2), have been synthesized and characterized by CHN elemental analysis as well as FT-IR, 1H NMR, absorption and emission spectroscopy, thermal analysis and analyzed structurally
1/2