302-97-6

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Evolution of enzymatic activities in the orotidine 5'-monophosphate decarboxylase suprafamily: mechanistic evidence for a proton relay system in the active site of 3-keto-L-gulonate 6-phosphate decarboxylase.

Wen Shan Yew et al.

Biochemistry, 43(21), 6427-6437 (2004-05-26)

3-Keto-L-gulonate 6-phosphate decarboxylase (KGPDC) and orotidine 5'-monophosphate decarboxylase (OMPDC) are homologous enzymes that share the (beta/alpha)(8)-fold but catalyze mechanistically distinct reactions [Wise, E., Yew, W. S., Babbitt, P. C., Gerlt, J. A., and Rayment, I. (2002) Biochemistry 41, 3861-3869]. KGPDC

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