442593

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Octahedral Group 4 Metal Complexes That Contain Amine, Amido, and Aminopyridinato Ligands: Synthesis, Structure, and Application in alpha-Olefin Oligo- and Polymerization.

Hans Fuhrmann et al.

Inorganic chemistry, 35(23), 6742-6745 (1996-11-06)

The reaction of trimethylsilyl-substituted 2-aminopyridines with mixed chloro(dialkylamido)metal complexes (titanium and zirconium) leads via amine elimination to octahedral group 4 metal complexes that contain amine, amido, and aminopyridinato ligands. The X-ray crystal structure analyses of (4-Me-TMS-APy)(NMe(2))(HNMe(2))TiCl(2) (1) (crystallographic data: P2(1)/c

Borane-catalysed postpolymerisation modification of the Si-H bonds in poly(phenylsilane).

P T K Lee et al.

Dalton transactions (Cambridge, England : 2003), 46(27), 8818-8826 (2017-04-01)

B(C

Numerical Simulations and In Situ Optical Microscopy Connecting Flow Pattern, Crystallization, and Thin-Film Properties for Organic Transistors with Superior Device-to-Device Uniformity.

Jeong-Chan Lee et al.

Advanced materials (Deerfield Beach, Fla.), 32(48), e2004864-e2004864 (2020-10-22)

Currently, due to the lack of precise control of flow behavior and the understanding of how it influences thin-film crystallization, strict tuning of thin-film properties during solution-based coating is difficult. In this work, a continuous-flow microfluidic-channel-based meniscus-guided coating (CoMiC) is

Organometallics, 15, 3600-3600 (1996)

Facile heterolytic cleavage of dihydrogen by phosphines and boranes.

Gregory C Welch et al.

Journal of the American Chemical Society, 129(7), 1880-1881 (2007-01-31)

Selective Ammonia-Sensing Platforms Based on a Solution-Processed Film of Poly(3-Hexylthiophene) and p-Doping Tris(Pentafluorophenyl)Borane.

Alem Araya Meresa et al.

Polymers, 12(1) (2020-01-18)

Here, we fabricate ammonia sensors based on organic transistors by using poly(3-hexylthiophene) (P3HT) blended with tris(pentafluorophenyl)borane (TPFB) as an active layer. As TPFB is an efficient p-type dopant for P3HT, the current level of the blend films can be easily

Microfluidic Separation of Ethylene and Ethane Using Frustrated Lewis Pairs.

Dan Voicu et al.

ChemSusChem, 8(24), 4202-4208 (2015-11-27)

Separation of gaseous olefins and paraffins is one of the most important separation processes in the industry. Development of new cost-effective technologies aims at reducing the high energy consumption during the separation process. Here, we took advantage of the reaction

Journal of the American Chemical Society, 118, 10008-10008 (1996)

Guanidinium-Assisted Surface Matrix Engineering for Highly Efficient Perovskite Quantum Dot Photovoltaics.

Xufeng Ling et al.

Advanced materials (Deerfield Beach, Fla.), 32(26), e2001906-e2001906 (2020-05-26)

Metal halide perovskite quantum dots (Pe-QDs) are of great interest in new-generation photovoltaics (PVs). However, it remains challenging in the construction of conductive and intact Pe-QD films to maximize their functionality. Herein, a ligand-assisted surface matrix strategy to engineer the

An Organic Borate Salt with Superior p-Doping Capability for Organic Semiconductors.

Berthold Wegner et al.

Advanced science (Weinheim, Baden-Wurttemberg, Germany), 7(17), 2001322-2001322 (2020-10-01)

Molecular doping allows enhancement and precise control of electrical properties of organic semiconductors, and is thus of central technological relevance for organic (opto-) electronics. Beyond single-component molecular electron acceptors and donors, organic salts have recently emerged as a promising class

Reactivity of Amine/E(C6F5)3 (E = B, Al) Lewis Pairs toward Linear and Cyclic Acrylic Monomers: Hydrogenation vs. Polymerization.

Jiawei Chen et al.

Molecules (Basel, Switzerland), 20(6), 9575-9590 (2015-05-29)

This work reveals the contrasting reactivity of amine/E(C6F5)3 (E = B, Al) Lewis pairs toward linear and cyclic acrylic monomers, methyl methacrylate (MMA) and biorenewable γ-methyl-α-methylene-γ-butyrolactone (γMMBL). While mixing of 2,2,6,6-tetramethylpiperidine (TMP) and B(C6F5)3 leads to a frustrated Lewis pair

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