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Maria V Vavoura et al.
Molecules (Basel, Switzerland), 20(2), 1922-1940 (2015-01-30)
Volatile compounds, physicochemical and sensory attributes of four sweet cherry cultivars (Canada giant, Ferrovia, Lapins and Skeena) grown in Northern Greece were determined. Eighteen volatile compounds were identified and semi-quantified in cherries using solid phase micro extraction in combination with
David Quesnel et al.
Journal of hazardous materials, 132(2-3), 253-260 (2005-11-24)
Removal rates of acetone and methyl isobutyl ketone (MIBK) were determined singularly and in combination in batch experiments employing an acclimatized activated sludge from a pilot system treating an organic chemical manufacturer industrial wastewater, as well as during the course
Ismail Inci
Biotechnology progress, 23(5), 1171-1179 (2007-09-07)
Equilibrium and kinetic studies for the extraction of succinic acid from aqueous solution with tridodecylamine diluted in MIBK are reported. All measurements were carried out at 298.15 K. The extent to which the organic phase may be loaded with succinic
Shu-Guang Fang et al.
Preparative biochemistry & biotechnology, 40(1), 38-45 (2009-12-22)
Enzymatic hydrolysis of penicillin G for production of 6-amino-penicillanic-acid (6-APA) was achieved by using penicillin G acylase as catalyst in an aqueous-methylisobutyl ketone (MIBK) system. The optimization was carried out and it was found that the best conversion was improved
Danvir Mark C Farnazo et al.
Bioprocess and biosystems engineering, 35(4), 579-590 (2011-10-01)
Biodegradations of methyl ethyl ketone and methyl isobutyl ketone were performed in intermittent biotrickling filter beds (ITBF) operated at two different trickling periods: 12 h/day (ITBF-12) and 30 min/day (ITBF-0.5). Ralstonia sp. MG1 was able to degrade both ketones as
Vincent W Chen et al.
Optics express, 22(10), 12316-12326 (2014-06-13)
Cuboid-shaped organic microcavities containing a pyrromethene laser dye and supported upon a photonic crystal have been investigated as an approach to reducing the lasing threshold of the cavities. Multiphoton lithography facilitated fabrication of the cuboid cavities directly on the substrate
Peng Wang et al.
ChemSusChem, 5(12), 2390-2396 (2012-11-08)
Pd-doped propyl sulfonic acid-functionalized hollow nanospheres proved to be efficient bifunctionalized catalysts for the one-pot synthesis of methyl isobutyl ketone (MIBK) from acetone and hydrogen in liquid phase. These hollow nanospheres exhibited a higher activity than their bulk mesoporous counterparts
Ting-Ke Tseng et al.
Journal of hazardous materials, 122(1-2), 155-160 (2005-05-26)
Catalytic oxidation is one of the cost-effective technologies to solve the troublesome volatile organic compounds. This study treated methyl-isobutyl-ketone (MIBK) by a commercial catalyst, Pt/gamma-Al(2)O(3), in a fixed-bed reactor. The effects of operating factors, such as operating temperature, MIBK concentration
Daekeun Kim et al.
Chemosphere, 64(8), 1362-1368 (2006-02-10)
Single and ternary solute gas phase adsorption isotherms were conducted in this study to evaluate the effectiveness of a simple constant volume method, which was utilized by using Tedlar gas sampling bags as a constant volume batch reactor. For this
S J Borghoff et al.
Toxicology, 258(2-3), 131-138 (2009-05-12)
Male F-344 rats were administered corn oil (vehicle control), d-limonene (positive control, 300mg/kg), or MIBK (1000mg/kg) and female F-344 rats corn oil (vehicle control) or MIBK for 10 consecutive days by oral gavage. Approximately 24h after the final dose the
Smita Raghuvanshi et al.
Environmental technology, 31(1), 29-40 (2010-03-18)
The present study deals with the biofiltration of methyl isobutyl ketone (MIBK), which is considered to be a highly toxic volatile organic compound. It is released from the paint and petrochemical industries and is one of the major contributors to
David Quesnel et al.
Water research, 39(4), 677-687 (2005-02-15)
An industrial wastewater that was pretreated by an aerobic thermophilic bacterial consortium (THE) was subjected to additional treatability studies by granular activated carbon (GAC) and a conventional activated sludge (CAS). The removal of dissolved organic carbon (DOC) in both systems
E Euripidou et al.
Emergency medicine journal : EMJ, 21(5), 548-552 (2004-08-31)
The aim of this study is to describe the pattern of ill health after personal incapacitant spray (PIS) exposures reported to the National Poisons Information Service-London (NPIS-L) and the Chemical Incident Response Service and to evaluate the relation between sub-categories
Eric Loeser et al.
Journal of chromatography. A, 1216(15), 3409-3412 (2009-02-25)
It has recently been shown that the use of strong organic solvents as diluent is possible in RPLC, provided that the solvent used as diluent is retained more strongly by the column than the analytes in the sample. In this
3-heptanone vs. 4-methyl-2-pentanone as extracting solvents in atomic absorption spectrophotometry.
Everson RJ and Parker HE.
Analytical Chemistry, 46(13), 2040-2042 (1974)
Temperature dependence of 4-methyl-2-pentanone photochemistry.
Encina MV, et al.
Journal of Photochemistry, 4(1), 75-89 (1975)
Tomoyuki Yokota et al.
Proceedings of the National Academy of Sciences of the United States of America, 112(47), 14533-14538 (2015-11-11)
We report a fabrication method for flexible and printable thermal sensors based on composites of semicrystalline acrylate polymers and graphite with a high sensitivity of 20 mK and a high-speed response time of less than 100 ms. These devices exhibit
H J Shim et al.
Journal of chromatography. B, Biomedical applications, 656(2), 407-414 (1994-06-17)
A high-performance liquid chromatographic method was developed for the simultaneous determination of a new anthracycline, DA-125 (I), and its metabolites (M1, M2, M3, and M4) in rat plasma and urine using fluorescein as an internal standard. Compound I, a prodrug
Mao Ting et al.
The Science of the total environment, 390(1), 97-108 (2007-11-03)
Volatile organic compounds (VOCs) in the air of Beijing City were measured at the heights of 8, 32, 140 and 280 m on the Beijing 325 m meteorological tower in autumn 2005. Concentrations of fifty-five compounds were determined by quantitative
Andrew W Owen et al.
Analytica chimica acta, 849, 12-18 (2014-10-11)
A specially designed thermal vaporiser was used with a process mass spectrometer designed for gas analysis to monitor the esterification of butan-1-ol and acetic anhydride. The reaction was conducted at two scales: in a 150 mL flask and a 1L
Navideh Sadoughi et al.
Journal of agricultural and food chemistry, 63(11), 2877-2885 (2015-02-24)
An optimized method for the quantitation of volatile compounds responsible for off-aromas, such as earthy odors, found in wine and grapes was developed. The method involved a fast and simple headspace solid-phase microextraction-gas chromatography-mass spectrometry (HS-SPME-GC-MS) for simultaneous determination of
Shakil A Saghir et al.
Regulatory toxicology and pharmacology : RTP, 52(2), 180-188 (2008-09-16)
Methyl isobutyl ketone (MIBK) is a solvent used in numerous products and processes and may be present in the air of the workplace as a vapor. The American Conference of Governmental Industrial Hygienists (ACGIH) threshold limit value-time-weighted average (TLV-TWA) and
M D Nemec et al.
International journal of toxicology, 23(2), 127-143 (2004-06-19)
To evaluate whether methyl isobutyl ketone (MIBK) affects reproductive performance, a two-generation reproduction study was conducted. MIBK was administered to 30 Sprague-Dawley rats/sex/group via whole-body inhalation at concentrations of 0, 500, 1000, or 2000 ppm, 6 h daily, for 70
Catalytic behaviors of silica-supported starch-polysulfosiloxane-Pt complexes in asymmetric hydrogenation of 4-methyl-2-pentanone.
Huang K, et al.
Reactive functional Polymers, 50(3), 199-203 (2002)
National Toxicology Program technical report series, (538)(538), 1-236 (2007-06-09)
Methyl isobutyl ketone is used as a denaturant for rubbing alcohol; as a solvent for paints, varnishes, nitrocellulose, lacquers, and protective coatings; in industrial extraction processes; in dry-cleaning preparations; and in the synthesis of methyl isobutyl carbinol. Methyl isobutyl ketone
Kayoko Minakata et al.
Analytica chimica acta, 651(1), 81-84 (2009-09-08)
A rapid and sensitive electrospray ionization tandem mass spectrometric (ESI-MS-MS) procedure was developed for the determination of cyanide (CN(-)). CN(-) in biological fluids was reacted with NaAuCl(4) to produce dicyanogold, Au(CN)(2)(-), which was extracted with methyl isobutyl ketone (MIBK). One
Heloisa R Cadorim et al.
Talanta, 146, 203-208 (2015-12-24)
An analytical method for the determination of sulfur, as the tin mono-sulfide (SnS) molecule, in crude oil using high-resolution continuum source graphite furnace molecular absorption spectrometry (HR-CS GF MAS) has been developed. The molecular absorbance of the SnS has been
Ting-Ke Tseng et al.
Chemosphere, 61(4), 469-477 (2005-10-06)
Environmental catalysis also can refer to catalytic technologies for reducing emission of environmentally unacceptable compounds. Catalytic decomposition also is one of the cost-effective technologies to solve the troublesome volatile organic compounds. This study treated methyl isobutyl ketone (MIBK) by a
Ryuichi Kubota et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 854(1-2), 204-210 (2007-05-09)
An analytical method using a combination of solid-phase extraction (SPE) and gas chromatography with a flame thermionic detector (GC/FTD) was developed for determination of N-methyl-2-pyrrolidone (NMP), N-methylsuccinimide (MSI), and 2-hydroxy-N-methylsuccinimide (2-HMSI) in human urine. The SPE cartridge of poly(divinylbenzene/hydroxymethacrylate) used
Toshio Kawai et al.
Industrial health, 49(1), 24-29 (2010-09-09)
To facilitate urine sample preparation prior to head-space gas-chromatographic (HS-GC) analysis. Urine samples containing one of the five solvents (acetone, methanol, methyl ethyl ketone, methyl isobutyl ketone and toluene) at the levels of biological exposure limits were aspirated into a
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