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光催化_可见光催化_化学合成方法-默克生命科学
光催化合成的主要特性是在温和的反应条件下,通过单电子转移途径激活简单易得的起始原料,形成具有反应性的开壳物质。这些独特的开壳物质可以参与各种自由基捕获/淬灭反应,最终得到高价值的产物。
Recent Advances in the Catalytic Transformations
This article details the latest progress in synthesizing alkylsulfonyl fluorides through different approaches that utilize photoredox catalysis, electrocatalysis, transition-metal catalysis, and organocatalysis. The alkylsulfonyl fluorides thus prepared could be utilized further in sulfur(VI) fluoride exchange (SuFEx) click reactions.
Single-Electron Oxidation Transformations
Review SET mechanism in photoredox catalysis for sustainable reactions and rearrangement of oxaziridines.
Micro Photochemical Reactor
Photocatalysis in organic synthesis has grown with innovative methods using visible light, contributing to new research.
Nicewicz Photoredox Catalysts for Anti-Markovnikov Alkene Hydrofunctionalization
Explore Nicewicz Photoredox catalysts—photoexcitable acridinium salts for efficient, metal-free anti-Markovnikov hydrofunctionalizations.
KitAlysis™ Photocatalysis Reaction Screening Kit
PhotoKitAlysis Reaction Kit aids in cross-coupling reactions, offering pre-weighed components for optimization.
Scale-Up Guide: Photocatalysis Reaction
Scale-Up Guide for Photocatalysis Reaction to best enable scale-up success with High-Throughput Screening Kit.
Photoredox Iridium Catalyst for SET Cross-Coupling
Effective Csp2- and Csp-hybridized coupling reactions established for catalysis, expanding to multi-step Csp3-coupling.
Visible-light Photoredox Catalysis
The application of radical chemistry towards organic synthesis is well-developed and wide-reaching, though often hampered by a dependence on toxic radical initiators.
Step-by-Step Guide for KitAlysis™ High-Throughput Photocatalysis Reaction Screening Kit
Materials and procedure Step-by-Step Guide for Photocatalysis High-Throughput Reaction Screening Kit
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