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Rhodium(III)-catalyzed dehydrogenative Heck reaction of salicylaldehydes.
Zhuangzhi Shi et al.
Angewandte Chemie (International ed. in English), 51(32), 8092-8096 (2012-06-30)
Yinfeng Zhang et al.
Proceedings of the National Academy of Sciences of the United States of America, 110(17), 6657-6662 (2013-04-10)
An efficient method has been developed for the salicylaldehyde ester-mediated ligation of unprotected peptides at serine (Ser) or threonine (Thr) residues. The utility of this peptide ligation approach has been demonstrated through the convergent syntheses of two therapeutic peptides--ovine-corticoliberin and
Ziyad A Taha et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 81(1), 317-323 (2011-07-15)
Eight new lanthanide metal complexes [LnL(NO(3))(2)]NO(3) {Ln(III) = Nd, Dy, Sm, Pr, Gd, Tb, La and Er, L = bis-(salicyladehyde)-1,3-propylenediimine Schiff base ligand} were prepared. These complexes were characterized by elemental analysis, thermogravimetric analysis (TGA), molar conductivity measurements and spectral
Joachim Morrens et al.
Neuron, 106(1), 142-153 (2020-02-07)
Dopamine neurons mediate the association of conditioned stimuli (CS) with reward (unconditioned stimuli, US) by signaling the discrepancy between predicted and actual reward during the US. Some theoretical models suggest that learning is also influenced by the salience or associability
İsmet Kaya et al.
Journal of fluorescence, 25(3), 663-673 (2015-03-17)
A series of diimine Schiff bases and their polymers were synthesized via the oxidative polycondensation reaction. The structures of the compounds were confirmed by (1)H-NMR, (13)C-NMR, FT-IR and UV-vis spectral measurements. Electrochemical and optical band gap values of synthesized compounds
Eri Kamii et al.
Shokuhin eiseigaku zasshi. Journal of the Food Hygienic Society of Japan, 52(5), 276-280 (2011-12-28)
In this study, we evaluated the antibacterial activity of essential oil vapors against histamine-producing bacteria Morganella morganii NBRC3848 and Raultella planticola NBRC3317. We measured the minimum inhibitory dose (MID) of 14 essential oils towards these two strains. Allyl isothiocyanate (AIT)
Chao-Bin Xue et al.
Bioorganic & medicinal chemistry, 15(5), 2006-2015 (2007-01-30)
Phenoloxidase (PO), also known as tyrosinase, is a key enzyme in insect development, responsible for catalyzing the hydroxylation of tyrosine into o-diphenols and the oxidation of o-diphenols into o-quinones. Inhibition of PO may provide a basis for novel environmentally friendly
Xianglin Shi et al.
The Journal of organic chemistry, 77(2), 1154-1160 (2011-12-17)
Mild reaction conditions for Petasis reactions of substituted salicylaldehydes with various amines and arylboronic acids in the presence of molecular sieves were developed. Molecular sieves (MS) significantly accelerated the reaction rates and drove the reactions to high conversions. The conditions
Gaosheng Yang et al.
Chemical communications (Cambridge, England), 48(47), 5880-5882 (2012-05-11)
A three-component cascade reaction of salicylaldehyde, malononitrile/cyanoacetate and nitromethane catalysed by chiral tertiary amino-thioureas was developed, which leads to the production of highly functionalized 2-amino-4H-chromenes in good yields with good to excellent enantioselectivities.
Balaji D Barve et al.
Organic letters, 16(7), 1912-1915 (2014-03-19)
Iron catalyzed oxidative coupling of salicylaldehydes with cyclic ethers proceeded through the direct α-C-H functionalization of ethers, forming the corresponding acetals in moderate to excellent yields. This is the first example of iron catalyzed selective C-O bond formation in the
Divya Singhal et al.
Materials science & engineering. C, Materials for biological applications, 58, 548-557 (2015-10-20)
A novel hydrazone, 1,3-bis (2-formylphenoxy) propane bis (2,4-dinitrophenyl hydrazine) (S) has been synthesized and characterized by the NMR, IR, CHNS, UV-Vis, Raman, TEM and XPS analysis. Upon the addition of monohydrogen phosphate (MHP) ion, sudden color change from light yellow
Rosa M Flores et al.
Journal of chromatography. A, 1418, 1-11 (2015-10-03)
Two, 3-step methods for derivatizing mono- and multi-functional species with carbonyl (CO), carboxylic acid (-COOH), and alcohol (-OH) moieties were compared and optimized. In Method 1, the CO, -COOH, and -OH moieties were converted (1) to methyloximes (R-CN-OCH3) with O-methylhydroxylamine
Biao Gu et al.
The Analyst, 140(8), 2778-2784 (2015-02-27)
A novel ratiometric fluorescent Hg(2+) detecting system was rationally developed based on the typical excited state intramolecular proton transfer (ESIPT) characteristic of the latent fluorophore, 2-(1-(p-tolyl)-1H-phenanthro[9,10-d]imidazol-2-yl)phenol (Pol) and the Hg(2+)-mediated cleavage of the vinyl group. The probe responds selectively to
Junming Ho et al.
Journal of inorganic biochemistry, 119, 10-20 (2012-11-22)
A series of N,N-disubstituted salicylaldehyde semicarbazones (SSCs), HOC(6)H(4)CHN-NHCONR(2), and their rhenium(I) tricarbonyl complexes, [ReBr(CO)(3)(SSC)], have been synthesised and characterised by IR and (1)H NMR spectroscopy. Crystallographic analysis of the complex [ReBr(CO)(3)(H(2)Bu(2))] (H(2)Bu(2)=SSC where R=Bu(n)) showed that the SSC acts as
Pipas Saha et al.
Organic & biomolecular chemistry, 10(12), 2470-2481 (2012-02-22)
An efficient method for the synthesis of 2,3,5,6-tetrasubstituted tetrahydropyrans has been developed from the reaction of aldehydes and ethyl 2-(1-hydroxyalkyl/hydroxy(phenyl)methyl)-5-methylhex-4-enoate using (3,5)-oxonium-ene reaction promoted by boron trifluoride etherate in good yields under mild conditions.
V Vinod Kumar et al.
Analytica chimica acta, 842, 57-62 (2014-08-17)
Highly selective label free colorimetric sensor based on AgNPs stabilized by phenolic chelating ligand, N,N'-bis(2-hydroxybenzyl)-1,2-diaminobenzene (1), for NO(2-) anions has been developed. Addition of NO(2-) showed selective decolourisation of brownish yellow colour of 1-AgNPs with the detection limit of 10(-7)M.
Soleiman Hisaindee et al.
Journal of fluorescence, 22(2), 677-683 (2011-11-05)
Salicylaldehyde was found to have a high selectivity for zinc ions with simultaneous enhancement of fluorescence in aqueous buffer solution at optimum pH 8.5. The stoichiometry of the complex was determined to be 1:1 with a K(a) value of 3.4
Salicylaldehyde is a characteristic aroma component of buckwheat groats.
Janes D & Kreft S.
Food Chemistry, 109(2), 293-298 (2008)
Patrícia de Almeida Machado et al.
Acta tropica, 148, 120-127 (2015-04-29)
Leishmaniasis is a group of disease caused by different species of the parasite Leishmania affecting millions of people worldwide. Conventional therapy relies on multiple parenteral injections with pentavalent antimonials which exhibit high toxicity and various side effects have been reported.
Eila Pelttari et al.
Zeitschrift fur Naturforschung. C, Journal of biosciences, 66(11-12), 571-580 (2012-02-23)
Substituted salicylaldehydes are potent antibacterial and antifungal agents and may have chemotherapeutic potential. In the clinical setting, the minimal inhibitory concentration (MIC) as well as the minimal bactericidal and fungicidal concentrations (MBC and MFC, respectively) are of fundamental interest. Therefore
Walfrido Bispo Júnior et al.
Molecules (Basel, Switzerland), 16(8), 6902-6915 (2011-08-17)
Salicylaldehyde 2-chlorobenzoyl hydrazone (H(2)LASSBio-466), salicylaldehyde 4-chlorobenzoyl hydrazone (H(2)LASSBio-1064) and their complexes [Zn(LASSBio-466)H(2)O](2) (1) and [Zn(HLASSBio-1064)Cl](2) (2) were evaluated in animal models of peripheral and central nociception, and acute inflammation. All studied compounds significantly inhibited acetic acid-induced writhing response. Upon coordination
Vinicius Z Mota et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 99, 110-115 (2012-10-16)
The Schiff base N,N'-bis(salicylidene)-o-phenylenediamine (salophen) was prepared by the condensation of salicylaldehyde with o-phenylenediamine in ethanol solution. The compound was characterized by elemental analysis, infrared (IR), (1)H, (13)C and (1)H(15)N HMBC nuclear magnetic resonance (NMR) spectroscopic measurements, and also by
Jesús F Arteaga et al.
Molecules (Basel, Switzerland), 17(5), 5126-5138 (2012-05-05)
Antioxidant activity of a number of small (low molecular weight) natural compounds found in spices, condiments or drugs (gallic acid, sesamol, eugenol, thymol, carvacrol, vanillin, salicylaldehyde, limonene, geraniol, 4-hexylresorcinol, etc.) has been evaluated using electrochemical and DPPH• radical scavenging measurements.
Mirta Rubčić et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 18(18), 5620-5631 (2012-03-27)
The Schiff base derived from salicylaldehyde and 2-amino-3-hydroxypyridine affords a diversity of solid forms, two polymorphic pairs of the enol-imino (D1 a and D1 b) and keto-amino (D2 a and D2 b) desmotropes. The isolated phases, identified by IR spectroscopy, X-ray crystallography, and (13)C
Zhimin Gu et al.
Cancer research, 75(11), 2211-2221 (2015-04-10)
Iron homeostasis is disrupted in multiple myeloma, a difficult-to-cure plasma cell malignancy with lytic bone lesions. Here, we systematically analyzed iron gene expression signature and demonstrated that mRNA expression of iron exporter ferroportin (FPN1) is significantly downregulated in myeloma cells
Abhijit Ghosh et al.
Dalton transactions (Cambridge, England : 2003), 44(26), 11797-11804 (2015-06-09)
A very simple molecule derived from salicylaldehyde and N-phenyl ethylenediamine (L1) functions as dual-mode ratiometric fluorescence "turn on" sensors for Zn(2+) and Al(3+) at two different wavelengths. The sensing is based on the combined effect of inhibition of excited-state intra-molecular
Wan Yen Lee et al.
Metallomics : integrated biometal science, 4(2), 188-196 (2011-12-03)
The copper(ii) complexes of two salicylaldehyde semicarbazones, HOC(6)H(4)CH[double bond, length as m-dash]N-NHCONR(2) [H(2)Bnz(2) (R = CH(2)Ph) and H(2)Bu(2) (R = Bu)], were evaluated for their DNA binding and cleavage properties by spectrophotometric DNA titration, ethidium bromide displacement assay and electrophoretic
Subhashree P Dash et al.
Journal of inorganic biochemistry, 144, 1-12 (2015-01-13)
Three dioxidovanadium(V) complexes [VO2L(1-3)] (1-3) [HL(1)=1-napthoyl hydrazone of 2-acetyl pyridine, HL(2)=2-furoyl hydrazone of 2-acetyl pyridine and H2L(3)=isonicotinoyl hydrazone of 2-hydroxy benzaldehyde] have been reported. All the complexes were characterized by various spectroscopy (IR, UV-visible and NMR) and the molecular structures
Khosro Mohammadi et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 107, 145-150 (2013-02-19)
Synthesis and evaluation of three new oxovanadium(IV) complexes, formed by the interaction of vanadyl acetylacetonate and the Schiff bases: 3,4-bis((E)-2-hydroxybenzylideneamino)benzoic acid (L(1)), 3,4-bis-((E)-2-hydroxy-3-methoxybenzylideneamino)benzoic acid (L(2)) and 3,4-bis((E)-2,4-dihydroxybenzylideneamino)benzoic acid (L(3)) in methanol. The complexes have been characterized and studied by IR
Stephen K Murphy et al.
Organic letters, 13(23), 6216-6219 (2011-11-09)
A method has been developed for the intermolecular hydroacylation of homoallyl alcohols with salicylaldehydes to furnish homoaldol products in 50-98% yields. The method also applies to the hydroacylation of 2-hydroxystyrenes. This work highlights the use of hydroacylation as a unified
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