CN
- Ligand-free Ni-catalyzed reductive cleavage of inert carbon-sulfur bonds.
Ligand-free Ni-catalyzed reductive cleavage of inert carbon-sulfur bonds.
Organic letters (2012-01-20)
Nekane Barbero, Ruben Martin
PMID22256952
摘要
A catalytic reductive cleavage of C(sp(2))- and C(sp(3))-SMe bonds under ligandless conditions is presented. The method is characterized by its wide scope and high chemoselectivity profile including challenging substrate combinations, allowing the design of orthogonal and site-selectivity approaches.