- Substituted m-phenylene bridges as strong ferromagnetic couplers for Cu(II)-bridge-Cu(II) magnetic interactions: new perspectives.
Substituted m-phenylene bridges as strong ferromagnetic couplers for Cu(II)-bridge-Cu(II) magnetic interactions: new perspectives.
Chemical communications (Cambridge, England) (2005-10-18)
Alok Ranjan Paital, Tamoghna Mitra, Debashis Ray, Wing Tak Wong, Jordi Ribas-Ariño, Juan J Novoa, Joan Ribas, Guillem Aromí
PMID16228025
摘要
Based on a combined theoretical-experimental study, we propose that substituted m-phenylene ligands (m-N-Phi-N) can act as tuneable strong ferromagnetic couplers connecting Cu(II) ions; a new complex presenting that bridge with J close to +15 cm(-1) has been suggested and synthesized.
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