Merck
CN
  • Controllable one-step synthesis of spirocycles, polycycles, and di- and tetrahydronaphthalenes from aryl-substituted propargylic alcohols.

Controllable one-step synthesis of spirocycles, polycycles, and di- and tetrahydronaphthalenes from aryl-substituted propargylic alcohols.

The Journal of organic chemistry (2008-08-07)
Wen Huang, Pengzhi Zheng, Zhengxing Zhang, Ruiting Liu, Zhenxia Chen, Xigeng Zhou
摘要

A novel, convenient, and efficient method has been developed for selective synthesis of spirocycle, polycycle, and di- and tetrahydronaphthalene systems from aryl-substituted propargylic alcohols by FeCl3- or TsOH-catalyzed multiple activations of unsaturated C-C bonds and C-H bonds.

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Sigma-Aldrich
苯磺酸, 98.0% (T)
Sigma-Aldrich
苯磺酸钠, 97%
Sigma-Aldrich
苯磺酸, technical grade, 90%