- o-Semiquinonato and o-iminosemiquinonato rhodium complexes. EPR study of the reactions in coordination sphere of rhodium.
o-Semiquinonato and o-iminosemiquinonato rhodium complexes. EPR study of the reactions in coordination sphere of rhodium.
Journal of magnetic resonance (San Diego, Calif. : 1997) (2011-02-11)
M P Bubnov, I A Teplova, K A Kozhanov, G A Abakumov, V K Cherkasov
PMID21306927
摘要
The number of dicarbonyl-o-semiquinonato (o-iminosemiquinonato) rhodium complexes was isolated and characterized. Some reactions of these compounds with tertiary phosphines (substitution, addition) were studied by EPR in solution using o-semiquinones (o-iminosemiquinones) as spin labels.