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  • Differences of crystal structure and dynamics between a soft porous nanocrystal and a bulk crystal.

Differences of crystal structure and dynamics between a soft porous nanocrystal and a bulk crystal.

Chemical communications (Cambridge, England) (2011-06-11)
Yuh Hijikata, Satoshi Horike, Daisuke Tanaka, Juergen Groll, Motohiro Mizuno, Jungeun Kim, Masaki Takata, Susumu Kitagawa
摘要

We have demonstrated downsizing effects of the soft porous crystal, [Zn(isophthalate)(4,4'-bipyridyl)](n) (CID-1), on the adsorption behavior between CID-1 and CID-1 nanocrystal (NCID-1). The difference results from the packing crystal structures and the dynamics of the frameworks.

材料
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品牌
产品描述

Sigma-Aldrich
4,4′-联吡啶, 98%
Sigma-Aldrich
间苯二甲酸, 99%