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  • Hydrogenolysis of lignosulfonate into phenols over heterogeneous nickel catalysts.

Hydrogenolysis of lignosulfonate into phenols over heterogeneous nickel catalysts.

Chemical communications (Cambridge, England) (2012-04-24)
Qi Song, Feng Wang, Jie Xu
摘要

We report a strategy for the catalytic conversion of lignosulfonate into phenols over heterogeneous nickel catalysts. Aryl-alkyl bonds (C-O-C) and hydroxyl groups (-OH) are hydrogenated to phenols and alkanes, respectively, without disturbing the arenes. The catalyst is based on a naturally abundant element, and is recyclable and reusable.

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木质素磺酸 钠盐, average Mw ~52,000, average Mn ~7,000