- Ionothermal synthesis and structure analysis of an open-framework zirconium phosphate with a high CO2/CH4 adsorption ratio.
Ionothermal synthesis and structure analysis of an open-framework zirconium phosphate with a high CO2/CH4 adsorption ratio.
Angewandte Chemie (International ed. in English) (2011-07-09)
Lei Liu, Jiangfeng Yang, Jinping Li, Jinxiang Dong, Dubravka Sišak, Marisa Luzzatto, Lynne B McCusker
PMID21739548
摘要
Less is more: an open-framework zirconium phosphate with unusual 7-ring channels was synthesized ionothermally from a deep-eutectic solvent. This small-pore material displays a CO(2)/CH(4) adsorption ratio (17.3 at 1 bar) that is significantly higher than that of typical 8-ring materials, making it highly attractive for CO(2)/CH(4) separations.
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