N-Heterocyclic carbene complexes of rhodium: structure, stability and reactivity.

N-Heterocyclic carbene complexes of rhodium: structure, stability and reactivity.

Dalton transactions (Cambridge, England : 2003) (2008-08-09)

Jeremy M Praetorius, Cathleen M Crudden

摘要

The organometallic chemistry of N-heterocyclic carbene complexes of the transition metals has received significant attention over the past ten years, especially with respect to complexes of Pd and Ru. The present Perspective highlights the chemistry of NHC complexes of another important transition metal, Rh. The application of Rh-NHC complexes in the industrially significant reactions of hydrogenation and hydroformylation is described. In order to accurately assess the activity of these complexes, their stability must be carefully determined. Various synthetic routes to Rh-NHC complexes are also described.

材料

Product Number

品牌

产品描述

204218

Sigma-Aldrich

铑, powder, 99.95% trace metals basis

GF40539405

铑, foil, 25x25mm, thickness 0.1mm, as rolled, 99.9%

GF80841146

铑, foil, 25x25mm, thickness 0.15mm, as rolled, 99.9%

GF57675561

铑, foil, light tested, 25x25mm, thickness 0.05mm, as rolled, 99.9%

GF35442727

铑, foil, not light tested, 25x25mm, thickness 0.0005mm, permanent polyester support, 99.85%

GF36379345

铑, foil, light tested, 15x15mm, thickness 0.05mm, as rolled, 99.9%

GF74452316

铑, wire reel, 0.05m, diameter 0.5mm, as drawn, 99.9%

GF44569907

铑, foil, 25x25mm, thickness 0.125mm, as rolled, 99.9%

GF12568013

铑, foil, light tested, 25x25mm, thickness 0.05mm, as rolled, x-ray quality, 99.9%

GF49946417

铑, microfoil, disks, 10mm, thinness 0.50μm, specific density 620μg/cm², permanent mylar 3.5μm support, 99.99%

GF87742659

铑, foil, not light tested, 25x25mm, thickness 0.001mm, permanent polyester support, 99.85%

GF71687357

铑, microfoil, disks, 10mm, thinness 0.1μm, specific density 124μg/cm², permanent mylar 3.5μm support, 99.9%

GF72510364

铑, wire reel, 0.5m, diameter 0.25mm, hard, 99.9%

GF14938005

铑, microfoil, disks, 25mm, thinness 0.1μm, specific density 124μg/cm², permanent mylar 3.5μm support, 99.9%

GF64213680

铑, wire reel, 0.05m, diameter 0.12mm, as drawn, 99.9%

GF82366342

铑, foil, not light tested, 50x50mm, thickness 0.00025mm, permanent polyester support, 99.9%

GF96356559

铑, foil, light tested, 25x25mm, thickness 0.075mm, as rolled, 99.9%

GF04978963

铑, foil, not light tested, 10x10mm, thickness 0.012mm, as rolled, 99.9%

GF49036204

铑, foil, not light tested, 25x25mm, thickness 0.00075mm, permanent polyester support, 99.85%

GF06539979

铑, wire reel, 0.1m, diameter 0.5mm, as drawn, 99.9%

GF54466937

铑, wire reel, 0.5m, diameter 0.12mm, as drawn, 99.9%

GF83497652

铑, wire reel, 0.05m, diameter 1.0mm, as drawn, 99.9%

GF37207166

铑, wire reel, 0.1m, diameter 1.0mm, as drawn, 99.9%

GF37380089

铑, wire reel, 0.2m, diameter 0.25mm, hard, 99.9%

GF17514312

铑, foil, not light tested, 25x25mm, thickness 0.00025mm, permanent polyester support, 99.9%

GF24911726

铑, foil, not light tested, 25x25mm, thickness 0.012mm, as rolled, 99.9%

GF22634120

铑, foil, not light tested, 50x50mm, thickness 0.00075mm, permanent polyester support, 99.85%

GF45819995

铑, wire reel, 0.05m, diameter 0.25mm, hard, 99.9%

GF26710680

铑, wire reel, 0.1m, diameter 0.12mm, as drawn, 99.9%

GF27499045

铑, wire reel, 0.1m, diameter 0.25mm, hard, 99.9%