CN
- Multicomponent self-sorting of a Pd7 molecular boat and its use in catalytic Knoevenagel condensation.
Multicomponent self-sorting of a Pd7 molecular boat and its use in catalytic Knoevenagel condensation.
Chemical communications (Cambridge, England) (2013-01-09)
Dipak Samanta, Partha Sarathi Mukherjee
PMID23295651
摘要
Unique three-component self-assembly of a cis-blocked 90° Pd(II) acceptor with a mixture of tri- and tetra-imidazole donors led to the self-sorting of a Pd7 molecular boat with an internal nanocavity, which catalyses the Knoevenagel condensation of a series of aromatic aldehydes with 1,3-dimethylbarbituric acid and Meldrum's acid in aqueous media.
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