CN
- Reactions of Trimethylaluminium: Modelling the Chemical Degradation of Synthetic Lubricants.
Reactions of Trimethylaluminium: Modelling the Chemical Degradation of Synthetic Lubricants.
Chemistry (Weinheim an der Bergstrasse, Germany) (2016-10-30)
Jonathan Slaughter, Andrew J Peel, Andrew E H Wheatley
PMID27792841
摘要
In investigating and seeking to mimic the reactivity of trimethylaluminium (TMA) with synthetic, ester-based lubricating oils, the reaction of methyl propionate 1 was explored with 1, 2 and 3 equivalents of the organoaluminium reagent. Spectroscopic analysis points to the formation of the adduct 1(TMA) accompanied only by the low level 1:1 production of Me