227870
硝基乙烷
ReagentPlus®, 99.5%
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关于此项目
线性分子式:
CH3CH2NO2
化学文摘社编号:
分子量:
75.07
EC Number:
201-188-9
UNSPSC Code:
12352102
PubChem Substance ID:
Beilstein/REAXYS Number:
1209324
MDL number:
Assay:
99.5%
Bp:
114-115 °C (lit.)
Vapor pressure:
15.6 mmHg ( 20 °C)
InChI key
MCSAJNNLRCFZED-UHFFFAOYSA-N
InChI
1S/C2H5NO2/c1-2-3(4)5/h2H2,1H3
SMILES string
CC[N+]([O-])=O
vapor density
2.58 (vs air)
vapor pressure
15.6 mmHg ( 20 °C)
product line
ReagentPlus®
assay
99.5%
form
liquid
autoignition temp.
778 °F
expl. lim.
3.4 %
dilution
(for general lab use)
refractive index
n20/D 1.391 (lit.)
bp
114-115 °C (lit.)
mp
−90 °C (lit.)
solubility
acetone: soluble(lit.), alcohol: soluble(lit.), water: slightly soluble(lit.)
density
1.045 g/mL at 25 °C (lit.)
Quality Level
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Legal Information
ReagentPlus is a registered trademark of Merck KGaA, Darmstadt, Germany
signalword
Warning
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Aquatic Chronic 3 - Flam. Liq. 3 - Repr. 2
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
87.8 °F - closed cup
flash_point_c
31 °C - closed cup
法规信息
危险化学品
易制爆化学品
此项目有
S T Stokes et al.
The Journal of chemical physics, 129(6), 064308-064308 (2008-08-22)
Valence and dipole-bound negative ions of the nitroethane (NE) molecule and its clusters are studied using photoelectron spectroscopy (PES), Rydberg electron transfer (RET) techniques, and ab initio methods. Valence adiabatic electron affinities (EA(a)s) of NE, C(2)H(5)NO(2), and its clusters, (C(2)H(5)NO(2))(n)
Feng-Wu Liu et al.
Carbohydrate research, 344(18), 2439-2443 (2009-11-03)
Henry reactions of a novel higher sugar derivative, (1R)-(1,4:3,6-dianhydro-D-mannitol-2-yl)-1,4:3,6-dianhydro-D-fructose 5,5'-dinitrate (Alternate nomenclature: (1R)-(isomannid-2-yl)-1,4:3,6-dianhydro-D-fructose 5,5'-dinitrate), with nitromethane and nitroethane were studied. The kinetic and thermodynamic reactions with nitromethane under different conditions were carried out to afford (2S)- and (2R)-beta-nitroalcohols, respectively. But
Base-promoted diastereoselective addition of nitromethane and nitroethane to N-tert-butylsulfinyl imines: synthesis of N-protected α-amino acids and amino ketones.
Garcia-Mu?oz MJ, et al.
Tetrahedron Asymmetry, 25(4), 362-372 (2014)
Michael P Valley et al.
Bioorganic chemistry, 38(3), 115-119 (2010-01-09)
The flavoenzyme nitroalkane oxidase catalyzes the oxidation of primary and secondary nitroalkanes to the corresponding aldehydes and ketones plus nitrite. The structure of the enzyme shows that Ser171 forms a hydrogen bond to the flavin N5, suggesting that it plays
Enantioselective aza-Henry reaction with an N-sulfinyl urea organocatalyst.
MaryAnn T Robak et al.
Journal of the American Chemical Society, 129(49), 15110-15111 (2007-11-17)
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