185426
邻甲基苯胺
≥99%
别名:
2-氨基甲苯, 2-甲基苯胺
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关于此项目
线性分子式:
CH3C6H4NH2
化学文摘社编号:
分子量:
107.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-429-0
Beilstein/REAXYS Number:
741981
MDL number:
Assay:
≥99%
Form:
liquid
InChI key
RNVCVTLRINQCPJ-UHFFFAOYSA-N
InChI
1S/C7H9N/c1-6-4-2-3-5-7(6)8/h2-5H,8H2,1H3
SMILES string
Cc1ccccc1N
vapor density
3.7 (vs air)
vapor pressure
0.26 mmHg ( 25 °C)
assay
≥99%
form
liquid
autoignition temp.
899 °F
refractive index
n20/D 1.572 (lit.)
bp
199-200 °C (lit.), 89-90 °C/11 mmHg (lit.)
mp
−28 °C (lit.)
solubility
alcohol: soluble, diethyl ether: soluble, water: slightly soluble
density
1.008 g/mL at 25 °C (lit.)
Quality Level
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General description
在HCl介质中，以过硫酸铵为氧化剂，邻甲苯胺与苯胺发生化学氧化聚合。
Application
邻甲苯胺用于测定生物材料中的葡萄糖。它被用作合成聚(邻甲苯胺)和铜纳米颗粒复合材料的前体。
signalword
Danger
Hazard Classifications
Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 1B - Eye Irrit. 2
存储类别
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
wgk
WGK 3
flash_point_f
185.0 °F - closed cup
flash_point_c
85 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
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A T Smit et al.
Bioresource technology, 243, 994-999 (2017-07-30)
Enzymatic cellulose hydrolysis of pretreated wheat straw pulp to glucose is enhanced when the hydrolysis is performed in the presence of an aqueous extract of the wheat straw. A relative digestibility increase of about 10% has been observed for organosolv
Oxidative copolymers of aniline with o-toluidine: Their structure and thermal properties.
Huang M-R, et al.
Journal of Applied Polymer Science, 81(8), 1838-1847 (2001)
In situ synthesis of copper nanoparticles and poly (< i> o</i>-toluidine): A metal-polymer composite material.
Mallick K, et al.
Eur. Polymer J., 42(3), 670-675 (2006)
Ivo Kalkman et al.
Physical chemistry chemical physics : PCCP, 11(21), 4311-4318 (2009-05-22)
The rotationally resolved spectrum of the o-toluidine S(1)<-- S(0) origin was measured using laser induced fluorescence spectroscopy. From the resulting spectrum torsional barriers to internal rotation of the methyl group were derived, which resulted in S(0) state values of V(3)
Emna Hmani et al.
Journal of hazardous materials, 170(2-3), 928-933 (2009-06-23)
Electrochemical oxidation of O-toluidine (OT) was studied by galvanostatic electrolysis using lead dioxide (PbO2) and boron-doped diamond (BDD) as anodes. The influence of operating parameters, such as current density, initial concentration of OT and temperature was investigated. Measurements of chemical
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