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线性分子式:
HOOCC6H4COOK
化学文摘社编号:
分子量:
204.22
NACRES:
NA.21
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
212-889-4
MDL number:
Beilstein/REAXYS Number:
3637128
Assay:
99.95-100.05% dry basis
Grade:
ACS reagent
Form:
crystals
Solubility:
water: soluble (93 g/l at 30 °C (86 °F))
产品名称
邻苯二甲酸氢钾, ACS reagent, acidimetric standard
InChI key
IWZKICVEHNUQTL-UHFFFAOYSA-M
InChI
1S/C8H6O4.K/c9-7(10)5-3-1-2-4-6(5)8(11)12;/h1-4H,(H,9,10)(H,11,12);/q;+1/p-1
SMILES string
[K+].OC(=O)c1ccccc1C([O-])=O
grade
ACS reagent
assay
99.95-100.05% dry basis
form
crystals
quality
acidimetric standard
impurities
≤0.002% S compounds, ≤0.003% Cl compounds, ≤0.005% insolubles
pH
4.00-4.02 (25.0 °C±0.2 °C, 0.05 M)
mp
295-300 °C (dec.) (lit.)
solubility
water: soluble (93 g/l at 30 °C (86 °F))
Quality Level
anion traces
chlorine and bromine (as Cl-): ≤0.003%, sulfur compounds (as SO42-): ≤0.002%
cation traces
Fe: ≤5 ppm, Na: ≤0.005%, heavy metals: ≤5 ppm (by ICP)
functional group
carboxylic acid
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Application
邻苯二甲酸氢钾可用作酸量滴定的一级标准品,也可用于制备用于 pH 校准的邻苯二甲酸氢钾缓冲液。
存储类别
13 - Non Combustible Solids
wgk
WGK 1
flash_point_f
387.1 °F - Pensky-Martens closed cup
flash_point_c
197.3 °C - Pensky-Martens closed cup
ppe
Eyeshields, Gloves, type N95 (US)
2, 4, 6-Trinitrobenzoic acid as a primary standerd in acidimetry.
Smith GF and Wilkins DH.
Analytica Chimica Acta, 8, 209-216 (1953)
Determination of standard pH values for potassium hydrogen phthalate reference buffer solutions in 10, 20, 50, 64 and 84.2 wt per cent methanol/water mixed solvents at temperatures from 283.15 to 313.15 K.
Mussini T, et al.
Electrochimica Acta, 28(11), 1593-1598 (1983)
J M Padró et al.
Talanta, 107, 95-102 (2013-04-20)
Dispersive ionic liquid-liquid microextraction combined with liquid chromatography and UV detection was used for the determination of two antichagasic drugs in human plasma: nifurtimox and benznidazole. The effects of experimental parameters on extraction efficiency-the type and volume of ionic liquid
Martha M Téllez-Rojo et al.
The Science of the total environment, 461-462, 386-390 (2013-06-12)
Previous studies suggest that prenatal phthalate exposure affects neurodevelopment and behavior during the first years of life. To evaluate the effect of maternal urinary concentrations of phthalate metabolites during pregnancy on mental and psychomotor development in children 24-36 months of
Randi J Bertelsen et al.
Environmental health perspectives, 121(2), 251-256 (2012-11-21)
High-molecular-weight phthalates in indoor dust have been associated with asthma in children, but few studies have evaluated phthalate biomarkers in association with respiratory outcomes. We explored the association between urinary concentrations of phthalate metabolites and current asthma. In a cross-sectional
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