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关键词:'Z744061SIAL'
facet content type:Technical Article
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可见光光氧化还原催化
自由基化学在有机合成中的应用已经过充分发展且影响广泛,但常常受制于对有毒自由基引发剂的依赖。
Visible-light Photoredox Catalysis
The application of radical chemistry towards organic synthesis is well-developed and wide-reaching, though often hampered by a dependence on toxic radical initiators.
Asymmetric Catalysis with Chiral Oxazaborolidinium Ions (COBIs)
Learn about the applications of chiral oxazaborolidinium ions (COBIs) as Lewis acid catalysts in different asymmetric reactions such as cyclopropanation, epoxidation, and radical reactions along with details of their catalytic action.
Recent Advances in the Catalytic Transformations
This article details the latest progress in synthesizing alkylsulfonyl fluorides through different approaches that utilize photoredox catalysis, electrocatalysis, transition-metal catalysis, and organocatalysis. The alkylsulfonyl fluorides thus prepared could be utilized further in sulfur(VI) fluoride exchange (SuFEx) click reactions.
Fluorescent Retinoid Probes
Fluorescent retinoic acid analogues for use in cellular imaging, protein-ligand binding assays, and flow cytometry to bypass traditional problems associated with fluorescent probes.
Photoredox Iridium Catalyst for SET Cross-Coupling
Effective Csp2- and Csp-hybridized coupling reactions established for catalysis, expanding to multi-step Csp3-coupling.
Reducing Organic Photoredox Catalysts for Visible Light-Driven Polymer and Small Molecule Synthesis
Photoredox catalysis is a powerful synthetic methodology to form challenging covalent bonds using light irradiation. It is effective for light-driven polymer and small molecule synthesis.
Nicewicz Photoredox Catalysts for Anti-Markovnikov Alkene Hydrofunctionalization
Explore Nicewicz Photoredox catalysts—photoexcitable acridinium salts for efficient, metal-free anti-Markovnikov hydrofunctionalizations.
Visible-Light-Mediated Reactions under Mild Conditions
This review provides a summary of recent approaches in developing green methods for visible-light-mediated reactions that operate under mild conditions and avoid the need for toxic transition-metal catalysts or harsh reaction conditions.