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Merck
CN

727466

p-叠氮甲苯 溶液

~0.5 M in tert-butyl methyl ether, ≥95.0% (HPLC)

别名:

1-叠氮-4-甲苯 溶液, 4-甲基苯基叠氮化物 溶液, p-甲苯基叠氮化物 溶液

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关于此项目

经验公式(希尔记法):
C7H7N3
化学文摘社编号:
分子量:
133.15
UNSPSC Code:
12352200
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1841411
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产品名称

p-叠氮甲苯 溶液, ~0.5 M in tert-butyl methyl ether, ≥95.0% (HPLC)

InChI

1S/C7H7N3/c1-6-2-4-7(5-3-6)9-10-8/h2-5H,1H3

SMILES string

Cc1ccc(cc1)N=[N+]=[N-]

InChI key

YVXDRCDGBCOJHX-UHFFFAOYSA-N

assay

≥95.0% (HPLC)

form

liquid

concentration

~0.5 M in tert-butyl methyl ether

impurities

≤2.0% water

storage temp.

−20°C

Quality Level

Application

4-Azidotoluene solution may be used for the functionalization at the axial position of boron subphthalocyanines with a terminal acetylene functionality via copper(I)-catalyzed azide-alkyne cycloaddition in the presence of Hunig′s base.

General description

4-Azidotoluene is an aromatic azide generally used in copper(I)-catalyzed azide-alkyne cycloaddition reactions.

pictograms

FlameExclamation mark

signalword

Danger

hcodes

Hazard Classifications

Flam. Liq. 2 - Skin Irrit. 2

存储类别

3 - Flammable liquids

wgk

WGK 3

flash_point_f

-18.4 °F

flash_point_c

-28 °C

法规信息

危险化学品
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历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Acetylenic Scaffolding with Subphthalocyanines.
Gotfredsen H, et al.
European Journal of Organic Chemistry, 2016(1), 17-21 (2016)
Ju Eun Jeon et al.
Cell, 180(1), 176-187 (2020-01-11)
In response to biotic stress, plants produce suites of highly modified fatty acids that bear unusual chemical functionalities. Despite their chemical complexity and proposed roles in pathogen defense, little is known about the biosynthesis of decorated fatty acids in plants.
Cu-catalyzed azide? alkyne cycloaddition
Meldal M & Torn?e CW
Chemical Reviews, 108(8), 2952-3015 (2008)

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