727466
p-叠氮甲苯 溶液
~0.5 M in tert-butyl methyl ether, ≥95.0% (HPLC)
别名:
1-叠氮-4-甲苯 溶液, 4-甲基苯基叠氮化物 溶液, p-甲苯基叠氮化物 溶液
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关于此项目
经验公式（希尔记法）:
C7H7N3
化学文摘社编号:
分子量:
133.15
UNSPSC Code:
12352200
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
1841411
Assay:
≥95.0% (HPLC)
Form:
liquid
InChI
1S/C7H7N3/c1-6-2-4-7(5-3-6)9-10-8/h2-5H,1H3
SMILES string
Cc1ccc(cc1)N=[N+]=[N-]
InChI key
YVXDRCDGBCOJHX-UHFFFAOYSA-N
assay
≥95.0% (HPLC)
form
liquid
concentration
~0.5 M in tert-butyl methyl ether
impurities
≤2.0% water
storage temp.
−20°C
Quality Level
General description
4-Azidotoluene is an aromatic azide generally used in copper(I)-catalyzed azide-alkyne cycloaddition reactions.
Application
4-Azidotoluene solution may be used for the functionalization at the axial position of boron subphthalocyanines with a terminal acetylene functionality via copper(I)-catalyzed azide-alkyne cycloaddition in the presence of Hunig′s base.
signalword
Danger
hcodes
Hazard Classifications
Flam. Liq. 2 - Skin Irrit. 2
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
-18.4 °F
flash_point_c
-28 °C
法规信息
危险化学品
此项目有
Acetylenic Scaffolding with Subphthalocyanines.
Gotfredsen H, et al.
European Journal of Organic Chemistry, 2016(1), 17-21 (2016)
Ju Eun Jeon et al.
Cell, 180(1), 176-187 (2020-01-11)
In response to biotic stress, plants produce suites of highly modified fatty acids that bear unusual chemical functionalities. Despite their chemical complexity and proposed roles in pathogen defense, little is known about the biosynthesis of decorated fatty acids in plants.
Cu-catalyzed azide? alkyne cycloaddition
Meldal M & Torn?e CW
Chemical Reviews, 108(8), 2952-3015 (2008)
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