727466
p-叠氮甲苯 溶液
~0.5 M in tert-butyl methyl ether, ≥95.0% (HPLC)
别名:
1-叠氮-4-甲苯 溶液, 4-甲基苯基叠氮化物 溶液, p-甲苯基叠氮化物 溶液
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关于此项目
经验公式(希尔记法):
C7H7N3
化学文摘社编号:
分子量:
133.15
Beilstein:
1841411
MDL编号:
UNSPSC代码:
12352200
PubChem化学物质编号:
NACRES:
NA.22
方案
≥95.0% (HPLC)
表单
liquid
浓度
~0.5 M in tert-butyl methyl ether
杂质
≤2.0% water
储存温度
−20°C
SMILES字符串
Cc1ccc(cc1)N=[N+]=[N-]
InChI
1S/C7H7N3/c1-6-2-4-7(5-3-6)9-10-8/h2-5H,1H3
InChI key
YVXDRCDGBCOJHX-UHFFFAOYSA-N
一般描述
4-Azidotoluene is an aromatic azide generally used in copper(I)-catalyzed azide-alkyne cycloaddition reactions.
应用
4-Azidotoluene solution may be used for the functionalization at the axial position of boron subphthalocyanines with a terminal acetylene functionality via copper(I)-catalyzed azide-alkyne cycloaddition in the presence of Hunig′s base.
警示用语:
Danger
危险声明
危险分类
Flam. Liq. 2 - Skin Irrit. 2
储存分类代码
3 - Flammable liquids
WGK
WGK 3
闪点(°F)
-18.4 °F
闪点(°C)
-28 °C
法规信息
危险化学品
此项目有
Acetylenic Scaffolding with Subphthalocyanines.
Gotfredsen H, et al.
European Journal of Organic Chemistry, 2016(1), 17-21 (2016)
Ju Eun Jeon et al.
Cell, 180(1), 176-187 (2020-01-11)
In response to biotic stress, plants produce suites of highly modified fatty acids that bear unusual chemical functionalities. Despite their chemical complexity and proposed roles in pathogen defense, little is known about the biosynthesis of decorated fatty acids in plants.
Cu-catalyzed azide? alkyne cycloaddition
Meldal M & Torn?e CW
Chemical Reviews, 108(8), 2952-3015 (2008)
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