103608
3-硝基苯乙酸
99%
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关于此项目
线性分子式:
O2NC6H4CH2CO2H
化学文摘社编号:
分子量:
181.15
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
217-512-7
Beilstein/REAXYS Number:
2050088
MDL number:
Assay:
99%
Form:
solid
产品名称
3-硝基苯乙酸, 99%
InChI key
WUKHOVCMWXMOOA-UHFFFAOYSA-N
InChI
1S/C8H7NO4/c10-8(11)5-6-2-1-3-7(4-6)9(12)13/h1-4H,5H2,(H,10,11)
SMILES string
OC(=O)Cc1cccc(c1)[N+]([O-])=O
assay
99%
form
solid
mp
117-120 °C (lit.)
functional group
carboxylic acid
nitro
Quality Level
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Application
3-Nitrophenylacetic acid was used to study photodecarboxylation of nitrophenylacetate ions in aqueous solution. 3-Nitrophenylacetic acid was used in study to synthesize an azobenzene amino acid, having potent use as photo-inducible conformational switch in polypeptides.
General description
3-Nitrophenylacetic acid is obtained by mild oxidation of 4-amino phenylacetic acid using potassium peroxymonosulfate as oxidizing agent in acetone.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
法规信息
新产品
此项目有
Photodecarboxylation of nitrophenylacetate ions.
Margerum JD and Petrusis CT.
Journal of the American Chemical Society, 91(10), 2467-2472 (1969)
A mild oxidation of aromatic amines.
Webb KS and Seneviratne S.
Tetrahedron Letters, 36(14), 2377-2378 (1995)
Andreas Aemissegger et al.
Nature protocols, 2(1), 161-167 (2007-04-03)
The synthesis of an azobenzene amino acid (aa) for use as a photo-inducible conformational switch in polypeptides is described. The compound can be easily incorporated into an aa sequence by solid-phase peptide synthesis using standard 9-fluorenylmethoxycarbonyl methods. A reversible conformational
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