质量水平
方案
98%
折射率
n20/D 1.523 (lit.)
沸点
39-40 °C/1 mmHg (lit.)
溶解性
THF: soluble
密度
1.18 g/mL at 25 °C (lit.)
官能团
thioester
SMILES字符串
O=C1CCCS1
InChI
1S/C4H6OS/c5-4-2-1-3-6-4/h1-3H2
InChI key
KMSNYNIWEORQDJ-UHFFFAOYSA-N
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一般描述
γ-硫代丁酸内酯与缩水甘油基苯基醚共聚形成聚酯硫醚 。
应用
γ-硫代丁酸内酯被用于终止 ω 开环聚合-十五内酯合成双功能聚酯 。γ-硫代丁酸内酯还被用于研究木质素降解担子菌 云芝 对含硫杂环化合物的代谢机理。
Md Abdul Kafi et al.
Regenerative biomaterials, 7(2), 141-151 (2020-04-17)
Scaffold engineering has attracted significant attention for three-dimensional (3D) growth, proliferation and differentiation of stem cells in vitro. Currently available scaffolds suffer from issues such as poor ability for cell adhesion, migration and proliferation. This paper addresses these issues with
One-pot difunctionalization of poly (ω-pentadecalactone) with thiol-thiol or thiol-acrylate groups, catalyzed by Candida antarctica lipase B.
Takwa M, et al.
Macromolecular Rapid Communications, 27(22), 1932-1936 (2006)
K D Holland et al.
Brain research, 615(1), 170-174 (1993-06-25)
Effects of alkyl-substituted gamma-butyrolactones and gamma-thiobutyrolactones on [35S]t-butylbicyclophosphorothionate (35S-TBPS) dissociation from the picrotoxinin receptor were studied. Unlike picrotoxinin, these lactones accelerated the dissociation rate of 35S-TBPS. Thus, previous reports that these lactones change the Kd but not the Bmax of
Nishikubo et al.
Macromolecules, 31(15), 4746-4752 (1998-07-29)
Poly(ester-alt-sulfide) (polymer 1) was synthesized by the alternating copolymerization of glycidyl phenyl ether (GPE) with gamma-thiobutyrolactone (TBL) catalyzed by either quaternary onium salts or crown ether complexes. The copolymerization proceeded to produce polymer 1 with good yields in neat or
Jonathan Garel et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 12(15), 4144-4152 (2006-02-03)
Homocysteine thiolactone (tHcy) is deemed a risk factor for cardiovascular diseases and strokes, presumably because it acylates the side chain of protein lysine residues ("N-homocysteinylation"), thereby causing protein damage and autoimmune responses. We analysed the kinetics of hydrolysis and aminolysis
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