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Merck
CN

106496

1,2-双(二苯基膦)乙烷

97%

别名:

1,2-二(二苯基膦基)乙烷, Diphos, dppe

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关于此项目

线性分子式:
(C6H5)2PCH2CH2P(C6H5)2
化学文摘社编号:
分子量:
398.42
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
EC Number:
216-769-2
Beilstein/REAXYS Number:
761261
MDL number:
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Quality Level

assay

97%

reaction suitability

reagent type: ligand
reaction type: C-C Bond Formation, reagent type: ligand
reaction type: Carbonylations, reagent type: ligand
reaction type: Cycloadditions, reagent type: ligand
reaction type: Decarboxylations, reagent type: ligand
reaction type: Diels-Alder Reaction, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

mp

137-142 °C (lit.)

functional group

phosphine

SMILES string

C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4

InChI

1S/C26H24P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-20H,21-22H2

InChI key

QFMZQPDHXULLKC-UHFFFAOYSA-N

Application

用于获得混合金属簇。
Ligand for metal-catalyzed allylic alkylation; decarboxylation of allylic esters; 1,3-diene synthesis; cycloaddition reactions; carbonylation reactions.


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pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)



历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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相关内容

Phosphine Ligand Application Guide


David P Temelkoff et al.
Carbohydrate research, 341(10), 1645-1656 (2006-02-28)
Bis(diphenylphosphino)ethane (DPPE) reacts with pyranosyl azides derived from D-glucose and D-glucuronic acid in the presence of acid chlorides to yield the corresponding glycosyl amides. Reaction rates are comparable to those with triphenylphosphine, however, the byproduct phosphine oxide is easily removed
Fiaud, J.-C.; Malleron, J.-L.
Chemical Communications (Cambridge, England), 1159-1159 (1981)
Weiming Gao et al.
Inorganic chemistry, 45(23), 9169-9171 (2006-11-07)
The reaction of [Fe2(CO)6(mu-SCH2)2NCH2CH2N(mu-SCH2)2Fe2(CO)6] (1) with 1,2-bis(diphenylphosphino)ethane in the presence of Me3NO.2H2O affords two structurally different metallomacromolecules: a dimer of the type [{Fe2(CO)5(mu-SCH2)2NCH2CH2N(mu-SCH2)2Fe2(CO)5}(Ph2PCH2)2] (2) and a tetramer species containing eight iron centers with an overall formula of [{Fe2(CO)6(mu-SCH2)2NCH2CH2N(mu-SCH2)2Fe2(CO)5}2(Ph2PCH2)2] (3). Their



全球贸易项目编号

货号GTIN
106496-50G04061833544310
106496-10G04061838674111