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106496

1,2-双(二苯基膦)乙烷

97%

别名:

1,2-二(二苯基膦基)乙烷, Diphos, dppe

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关于此项目

线性分子式:
(C6H5)2PCH2CH2P(C6H5)2
化学文摘社编号:
1663-45-2
分子量:
398.42
UNSPSC Code:
12352002
NACRES:
NA.22
PubChem Substance ID:
24846735
EC Number:
216-769-2
Beilstein/REAXYS Number:
761261
MDL number:
MFCD00003047
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Quality Level

200

assay

97%

reaction suitability

reagent type: ligand
reaction type: C-C Bond Formation, reagent type: ligand
reaction type: Carbonylations, reagent type: ligand
reaction type: Cycloadditions, reagent type: ligand
reaction type: Decarboxylations, reagent type: ligand
reaction type: Diels-Alder Reaction, reagent type: ligand
reaction type: Heck Reaction, reagent type: ligand
reaction type: Negishi Coupling, reagent type: ligand
reaction type: Suzuki-Miyaura Coupling

mp

137-142 °C (lit.)

functional group

phosphine

SMILES string

C(CP(c1ccccc1)c2ccccc2)P(c3ccccc3)c4ccccc4

InChI

1S/C26H24P2/c1-5-13-23(14-6-1)27(24-15-7-2-8-16-24)21-22-28(25-17-9-3-10-18-25)26-19-11-4-12-20-26/h1-20H,21-22H2

InChI key

QFMZQPDHXULLKC-UHFFFAOYSA-N

Application

用于获得混合金属簇。
Ligand for metal-catalyzed allylic alkylation; decarboxylation of allylic esters; 1,3-diene synthesis; cycloaddition reactions; carbonylation reactions.

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pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H335

Hazard Classifications

STOT SE 3

target_organs

Respiratory system

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
MKCC4988
03810PD
03610PD
04010PD
03910PD

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相关内容

Phosphine Ligand Application Guide

Phosphine Ligand Application Guide

G D Hoke et al.
Molecular pharmacology, 39(1), 90-97 (1991-01-01)
Bis(diphenylphosphine)ethane (DPPE) and its gold coordination complexes have demonstrated antitumor activity in transplantable tumor models. This report describes the development of a P388 cell line (P388/DPPEc) that is resistant to DPPE and its analogues and the in vitro characterization of
Anne Westphal et al.
Inorganic chemistry, 51(10), 5748-5763 (2012-05-03)
The molybdenum(V) complex [Mo(O)Cl(3)dppe] [dppe = 1,2-bis(diphenylphosphino)ethane] is considered as a model system for a combined study of the electronic structure using UV/vis absorption and magnetic circular dichroism (MCD) spectroscopy. In order to determine the signs and MCD C-term intensities
Gleb A Silantyev et al.
Inorganic chemistry, 52(4), 1787-1797 (2013-01-30)
The combination of variable temperature (190-297 K) IR and NMR spectroscopy studies with quantum-chemical calculations at the DFT/B3PW91 and AIM level had the aim to determine the mechanism of proton transfer to CpRuH(dppe) (1, dppe = Ph(2)P(CH(2))(2)PPh(2)) and the structures
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全球贸易项目编号

货号GTIN
106496-50G04061833544310
106496-10G04061838674111