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Merck
CN

107743

5-降冰烯-2-基乙酸酯,内型和外型混合物

98%

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关于此项目

经验公式(希尔记法):
C9H12O2
化学文摘社编号:
分子量:
152.19
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
228-144-1
MDL number:
Assay:
98%
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assay

98%

refractive index

n20/D 1.47 (lit.)

bp

73-76 °C/14 mmHg (lit.)

density

1.044 g/mL at 25 °C (lit.)

SMILES string

CC(=O)OC1C[C@H]2C[C@@H]1C=C2

InChI

1S/C9H12O2/c1-6(10)11-9-5-7-2-3-8(9)4-7/h2-3,7-9H,4-5H2,1H3/t7-,8+,9?/m1/s1

InChI key

DRWRVXAXXGJZIO-WGTSGOJVSA-N

Application

5-Norbornen-2-yl acetate (mixture of endo and exo) was used to study the ring opening metathesis polymerization of norbornene catalysed by dinuclear complex Cp*2Os2Br4 (Cp*=pentamethylcyclopentadienyl) and related compounds.

Biochem/physiol Actions

5-Norbornen-2-yl acetate undergoes copolymerisation with ethylene by nickel catalyst system to form high molecular weight functionalized polyethylene bearing ester functionalities. -Norbornen-2-yl acetate is the starting reagent for synthesis of urea condensation products from a-dicarbonyl compounds using Bi (OTf)3 catalyst.


存储类别

10 - Combustible liquids

wgk

WGK 3

flash_point_f

143.6 °F - closed cup

flash_point_c

62 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

法规信息

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A Weissfloch et al.
Bioorganic & medicinal chemistry, 2(6), 493-500 (1994-06-01)
A practical integrated process, combining an enzymatic resolution step with a few chemical transformations, is described for the synthesis of (1R, 4R)- and (2S, 4S)-bicyclo[2.2.1]heptan-2,5-diones 1 of high enantiomeric purity, starting from a standard mixture of (+/-)-endo- and exo-2-acetoxy-5-norbornene.
Ring-opening metathesis polymerization of norbornene by Cp* 2Os2Br4 and related compounds.
Brumaghim JL and Girolami GS.
Organometallics, 18(10), 1923-1929 (1999)
Ethylene homopolymerization and copolymerization with functionalized 5-norbornen-2-yl monomers by a novel nickel catalyst system.
Diamanti SJ, et al.
Macromolecules, 36(26), 9731-9735 (2003)



全球贸易项目编号

货号GTIN
107743-25G04061836673574
107743-100G04061836681784