10905
氯丙酮
Wacker Chemie AG, ≥96.0% (GC)
别名:
MCA, 1-氯-2-丙酮, 氯-2-丙酮
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线性分子式:
ClCH2COCH3
化学文摘社编号:
分子量:
92.52
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-161-1
Beilstein/REAXYS Number:
605369
MDL number:
Assay:
≥96.0% (GC)
产品名称
氯丙酮, Wacker Chemie AG, ≥96.0% (GC)
InChI key
BULLHNJGPPOUOX-UHFFFAOYSA-N
InChI
1S/C3H5ClO/c1-3(5)2-4/h2H2,1H3
SMILES string
CC(=O)CCl
assay
≥96.0% (GC)
contains
~0.1% Drapex 39 as stabilizer
manufacturer/tradename
Wacker Chemie AG
refractive index
n20/D 1.432 (lit.)
bp
120 °C (lit.)
solubility
H2O: soluble 10 parts
alcohol: miscible
chloroform: miscible
diethyl ether: miscible
density
1.162 g/mL at 25 °C (lit.)
storage temp.
2-8°C
Quality Level
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Application
氯丙酮用于氯丙酮的微生物不对称还原合成手性 1,2-环氧丙烷。它用于通过气相色谱分析酸。它还用于和 1-((3-(萘并[2,1-b]呋喃-2-基)-1-苯基-1H-吡唑-4-基)亚甲基)-2-苯腙反应合成甲基噻唑衍生物。
General description
氯丙酮与L-脯氨酸酰胺催化的 4-硝基苯甲醛发生直接羟醛反应。它与羧酸反应形成酯衍生物。
Other Notes
可根据要求提供批量价格
signalword
Danger
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
95.0 °F - closed cup
flash_point_c
35 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Ashraf H F Abd El-Wahab et al.
Molecules (Basel, Switzerland), 16(1), 307-318 (2011-01-27)
Vilsmeier formylation of 2-(1-phenylhydrazonoethyl)naphtho[2,1-b]furan (2) gave 3-naphtho[2,1-b]furan-2-yl-1-phenyl-1H-pyrazole-4-carbaldehyde (3), which was reacted with C- and N-nucleophiles to afford naphthofuranpyrazol derivatives 4-8. Treatment of 2-[(3-(naphtho[2,1-b]furan-2-yl)-1-phenyl-1H-pyrazol-4-yl)methylene]-malononitrile (4a) with reactants having active hydrogen and Et₃N gave the corresponding pyrazoline, pyran and chromene addition product
Analysis of carboxylic acids by gas chromatography. Derivatisation using chloroacetone.
McCalley DV, et al.
Chromatographia, 18(6), 309-312 (1984)
Synthesis of optically pure 1, 2-epoxypropane by microbial asymmetric reduction of chloroacetone.
Weijers CAGM, et al.
Applied Microbiology and Biotechnology, 38(3), 297-300 (1992)
L-Proline amide-catalyzed direct asymmetric aldol reaction of aldehydes with chloroacetone.
He L, et al.
Tetrahedron, 62(2), 346-351 (2006)
M R Hollaway et al.
The Biochemical journal, 191(3), 811-826 (1980-12-01)
1. Chloroacetone (I) was shown to be an active-site-directed inhibitor of the aliphatic amidase (EC 3.5.1.4) from Pseudomonas aeruginosa strain PAC142.2. This inhibitor reacted with the enzyme in two stages: the first involving the reversible formation of an enzymically inactive
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