10905
氯丙酮
Wacker Chemie AG, ≥96.0% (GC)
别名:
MCA, 1-氯-2-丙酮, 氯-2-丙酮
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线性分子式:
ClCH2COCH3
化学文摘社编号:
分子量:
92.52
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
201-161-1
Beilstein/REAXYS Number:
605369
MDL number:
Assay:
≥96.0% (GC)
InChI key
BULLHNJGPPOUOX-UHFFFAOYSA-N
InChI
1S/C3H5ClO/c1-3(5)2-4/h2H2,1H3
SMILES string
CC(=O)CCl
assay
≥96.0% (GC)
contains
~0.1% Drapex 39 as stabilizer
manufacturer/tradename
Wacker Chemie AG
Quality Level
bp
120 °C (lit.)
solubility
H2O: soluble 10 parts, alcohol: miscible, chloroform: miscible, diethyl ether: miscible
density
1.162 g/mL at 25 °C (lit.)
storage temp.
2-8°C
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General description
氯丙酮与L-脯氨酸酰胺催化的 4-硝基苯甲醛发生直接羟醛反应。它与羧酸反应形成酯衍生物。
Application
氯丙酮用于氯丙酮的微生物不对称还原合成手性 1,2-环氧丙烷。它用于通过气相色谱分析酸。它还用于和 1-((3-(萘并[2,1-b]呋喃-2-基)-1-苯基-1H-吡唑-4-基)亚甲基)-2-苯腙反应合成甲基噻唑衍生物。
Other Notes
可根据要求提供批量价格
signalword
Danger
Hazard Classifications
Acute Tox. 2 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
3 - Flammable liquids
wgk
WGK 3
flash_point_f
95.0 °F - closed cup
flash_point_c
35 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
危险化学品
此项目有
Analysis of carboxylic acids by gas chromatography. Derivatisation using chloroacetone.
McCalley DV, et al.
Chromatographia, 18(6), 309-312 (1984)
Ashraf H F Abd El-Wahab et al.
Molecules (Basel, Switzerland), 16(1), 307-318 (2011-01-27)
Vilsmeier formylation of 2-(1-phenylhydrazonoethyl)naphtho[2,1-b]furan (2) gave 3-naphtho[2,1-b]furan-2-yl-1-phenyl-1H-pyrazole-4-carbaldehyde (3), which was reacted with C- and N-nucleophiles to afford naphthofuranpyrazol derivatives 4-8. Treatment of 2-[(3-(naphtho[2,1-b]furan-2-yl)-1-phenyl-1H-pyrazol-4-yl)methylene]-malononitrile (4a) with reactants having active hydrogen and Et₃N gave the corresponding pyrazoline, pyran and chromene addition product
Synthesis of optically pure 1, 2-epoxypropane by microbial asymmetric reduction of chloroacetone.
Weijers CAGM, et al.
Applied Microbiology and Biotechnology, 38(3), 297-300 (1992)
L-Proline amide-catalyzed direct asymmetric aldol reaction of aldehydes with chloroacetone.
He L, et al.
Tetrahedron, 62(2), 346-351 (2006)
Bridget W Alligood et al.
The Journal of chemical physics, 135(3), 034302-034302 (2011-07-27)
We use a combination of crossed laser-molecular beam scattering experiments and velocity map imaging experiments to investigate the three primary photodissociation channels of chloroacetone at 193 nm: C-Cl bond photofission yielding CH(3)C(O)CH(2) radicals, C-C bond photofission yielding CH(3)CO and CH(2)Cl
我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.
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