10906
氯乙醛缩二甲醇
Wacker Chemie AG, ≥99.0% (GC)
别名:
CADMA, 2-氯-1,1-二甲氧基乙烷, 二甲基氯乙缩醛
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线性分子式:
ClCH2CH(OCH3)2
化学文摘社编号:
分子量:
124.57
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-624-0
Beilstein/REAXYS Number:
1733700
MDL number:
Assay:
≥99.0% (GC)
InChI key
CRZJPEIBPQWDGJ-UHFFFAOYSA-N
InChI
1S/C4H9ClO2/c1-6-4(3-5)7-2/h4H,3H2,1-2H3
SMILES string
COC(CCl)OC
assay
≥99.0% (GC)
manufacturer/tradename
Wacker Chemie AG
Quality Level
bp
128-130 °C (lit.)
density
1.094 g/mL at 25 °C (lit.)
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General description
Chloroacetaldehyde dimethyl acetal is a clear, colorless liquid. It reacts with hydroxythiol to form hydroxy acetal.
Application
Chloroacetaldehyde dimethyl acetal can be used as a reactant to synthesize:
- 2-(chloromethyl)-4,7-dethyl-1,3-dioxepane
- 2-(chloromethyl)-5,6-benzo-1,3-dioxepane
- ketene dimethyl acetal
Chloroacetaldehyde dimethyl acetal was used to investigate the enzymes used for activation and transformation of vinyl chloride. It was also used for introducing O-(2,2-dimethoxyethyl) groups into amylose, dextran, and a linear (1→3)-β-D-glucan. Chloroacetaldehyde dimethyl acetal was utilised in the synthesis of ethoxyacetylide.
Other Notes
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
84.2 °F - closed cup
flash_point_c
29 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
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Coupling of polysaccharides activated by means of chloroacetaldehyde dimethyl acetal to amines or proteins by reductive amination.
B?gwald J, et al.
Carbohydrate Research, 148(1), 101-107 (1986)
Simple enols. 3. Stereochemistry of simple enols in solution.
Capon B
The Journal of Organic Chemistry, 49(2), 255-257 (1984)
Recent trends in the synthesis of carbazoles: an update.
Tetrahedron, 68(31), 6099-6121 (2012)
Activation of vinyl chloride to covalently bound metabolites: roles of 2-chloroethylene oxide and 2-chloroacetaldehyde.
F P Guengerich et al.
Biochemistry, 18(23), 5177-5182 (1979-11-13)
Camphor derived 1, 4-oxathianes for carbonyl epoxidation.
Tetrahedron Asymmetry, 9(10), 1801-1807 (1998)
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