10906
氯乙醛缩二甲醇
Wacker Chemie AG, ≥99.0% (GC)
别名:
CADMA, 2-氯-1,1-二甲氧基乙烷, 二甲基氯乙缩醛
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线性分子式:
ClCH2CH(OCH3)2
化学文摘社编号:
分子量:
124.57
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
202-624-0
Beilstein/REAXYS Number:
1733700
MDL number:
Assay:
≥99.0% (GC)
Quality Level
assay
≥99.0% (GC)
manufacturer/tradename
Wacker Chemie AG
refractive index
n20/D 1.415 (lit.)
bp
128-130 °C (lit.)
density
1.094 g/mL at 25 °C (lit.)
SMILES string
COC(CCl)OC
InChI
1S/C4H9ClO2/c1-6-4(3-5)7-2/h4H,3H2,1-2H3
InChI key
CRZJPEIBPQWDGJ-UHFFFAOYSA-N
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General description
Chloroacetaldehyde dimethyl acetal is a clear, colorless liquid. It reacts with hydroxythiol to form hydroxy acetal.
Application
Chloroacetaldehyde dimethyl acetal was used to investigate the enzymes used for activation and transformation of vinyl chloride. It was also used for introducing O-(2,2-dimethoxyethyl) groups into amylose, dextran, and a linear (1→3)-β-D-glucan. Chloroacetaldehyde dimethyl acetal was utilised in the synthesis of ethoxyacetylide.
Chloroacetaldehyde dimethyl acetal can be used as a reactant to synthesize:
- 2-(chloromethyl)-4,7-dethyl-1,3-dioxepane
- 2-(chloromethyl)-5,6-benzo-1,3-dioxepane
- ketene dimethyl acetal
Other Notes
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signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Chronic 3 - Flam. Liq. 3
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
84.2 °F - closed cup
flash_point_c
29 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
Recent trends in the synthesis of carbazoles: an update.
Tetrahedron, 68(31), 6099-6121 (2012)
Activation of vinyl chloride to covalently bound metabolites: roles of 2-chloroethylene oxide and 2-chloroacetaldehyde.
F P Guengerich et al.
Biochemistry, 18(23), 5177-5182 (1979-11-13)
Camphor derived 1, 4-oxathianes for carbonyl epoxidation.
Tetrahedron Asymmetry, 9(10), 1801-1807 (1998)
Coupling of polysaccharides activated by means of chloroacetaldehyde dimethyl acetal to amines or proteins by reductive amination.
B?gwald J, et al.
Carbohydrate Research, 148(1), 101-107 (1986)
Free radical ring-opening polymerization of 4, 7-dimethyl-2-methylene-1, 3-dioxepane and 5, 6-benzo-2-methylene-1, 3-dioxepane.
Bailey WJ
Macromolecules, 15(3), 711-714 (1982)
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| V800100-6X500G | 04061832760889 |
| V800101-500G | 04061832599229 |
| PHR1326-5G | 04061835233632 |
| NIST2193B | 04065266888737 |
| 202932-100G | 04061838765406 |
| 202932-5G | 04061838765420 |
| 21061-50G-F | 04061838771377 |
| 21067-25G | 04061835560059 |
| 21069-1KG | 04061838771438 |
| 239216-100G | 04061838787354 |
| 239216-1KG | 04061838787361 |
| 239216-500G | 04061838787378 |
| 1017071000 | 04027269077730 |
| 1020590500 | 04022536028439 |
| 1020590050 | 04022536028422 |
| 1020699025 | 04022536028729 |
| 1020669050 | 04022536028620 |
| 1024100050 | 04022536687643 |
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