116130
乙烯基膦酸二乙酯
97%
别名:
Vinylphosphonic acid diethyl ester
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关于此项目
线性分子式:
CH2=CHPO(OCH2CH3)2
化学文摘社编号:
分子量:
164.14
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
211-663-2
Beilstein/REAXYS Number:
507596
MDL number:
产品名称
乙烯基膦酸二乙酯, 97%
InChI key
DREPONDJUKIQLX-UHFFFAOYSA-N
InChI
1S/C6H13O3P/c1-4-8-10(7,6-3)9-5-2/h6H,3-5H2,1-2H3
SMILES string
CCOP(=O)(OCC)C=C
assay
97%
refractive index
n20/D 1.429 (lit.)
bp
202 °C (lit.)
density
1.068 g/mL at 25 °C (lit.)
functional group
phosphonate
storage temp.
2-8°C
Quality Level
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Application
乙烯基膦酸二乙酯已用于制备N-烷基-2-氨基乙基膦酸二乙酯。
乙烯基膦酸二乙酯（DEVP）可用作合成以下物质的前体：
它也可以用作单体单元，用于通过镧系元素络合物制备高分子量聚合物聚（二乙基乙烯基膦酸酯）。{18）
- α, β与芳基硼酸进行Pd催化的Mizoroki−Heck反应生成不饱和膦酸酯。
- 通过氮杂迈克尔（aza-Michael）反应与伯胺和仲胺缩合生成2-（芳基氨基）乙基膦酸酯。
它也可以用作单体单元，用于通过镧系元素络合物制备高分子量聚合物聚（二乙基乙烯基膦酸酯）。{18）
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
230.0 °F - closed cup
flash_point_c
110 °C - closed cup
ppe
Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)
Synthesis of 2-(arylamino) ethyl phosphonic acids via the aza-Michael addition on diethyl vinylphosphonate
Orm Nadine B, et al.
Tetrahedron, 69(1), 115-121 (2013)
Poly (vinylphosphonate) s synthesized by trivalent cyclopentadienyl lanthanide-induced group transfer polymerization
Salzinger S, et al.
Macromolecules, 44(15), 5920-5927 (2011)
Convenient synthesis of α, β-unsaturated phosphonates via a Mizoroki-Heck reaction of arylboronic acids with diethyl vinylphosphonate
Kabalka GW, et al.
Tetrahedron Letters, 45(24), 4685-4687 (2004)
Joachim E Klee et al.
Beilstein journal of organic chemistry, 5, 72-72 (2009-01-01)
Novel N-alkyl-N-(phosphonoethyl) substituted mono-, bis- and tris(meth)acrylamides 3 were synthesized by two different three-step reactions and characterized by IR, (1)H NMR and (13)C NMR spectroscopy as well as refractive index and viscosity. The phosphonoethyl substituted (meth)acrylamide monomers show improved hydrolytic
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