117722
1-金刚烷甲酰氯
95%
别名:
1-Adamantanecarboxylic acid chloride, 1-Chlorocarbonyladamantane
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关于此项目
经验公式（希尔记法）:
C11H15ClO
化学文摘社编号:
分子量:
198.69
Beilstein:
389960
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
95%
表单
solid
沸点
135-136 °C/10 mmHg (lit.)
mp
49-51 °C (lit.)
官能团
acyl chloride
SMILES字符串
ClC(=O)C12C[C@H]3C[C@H](C[C@H](C3)C1)C2
InChI
1S/C11H15ClO/c12-10(13)11-4-7-1-8(5-11)3-9(2-7)6-11/h7-9H,1-6H2/t7-,8+,9-,11-
InChI key
MIBQYWIOHFTKHD-KJZNFTALSA-N
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一般描述
1-金刚烷羰基氯与异丙基亚磷酸三乙胺反应生成混合酸酐，这是一种用于氢-膦酸盐 DNA 合成的有效封端试剂 。它是金属铟存在下苯甲醚 Friedel–Crafts 酰化反应的良好底物 。
应用
1-金刚烷羰基氯被用于制备高效的胺修饰的寡脱氧核苷酸，用于制备 DNA 微阵列 。
警示用语：
Danger
危险声明
危险分类
Skin Corr. 1B
补充剂危害
储存分类代码
8A - Combustible corrosive hazardous materials
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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