121207
4,4′-三亚甲基二哌啶
97%
别名:
1,3-二-4-哌啶基丙烷, 1,3-双（4-哌啶基）丙烷
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关于此项目
经验公式（希尔记法）:
C13H26N2
化学文摘社编号:
分子量:
210.36
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
240-941-6
MDL number:
Assay:
97%
InChI key
OXEZLYIDQPBCBB-UHFFFAOYSA-N
InChI
1S/C13H26N2/c1(2-12-4-8-14-9-5-12)3-13-6-10-15-11-7-13/h12-15H,1-11H2
SMILES string
C(CC1CCNCC1)CC2CCNCC2
assay
97%
mp
65-68.5 °C (lit.)
Quality Level
General description
4,4′-三亚甲基二吡啶在硫磺存在下与二乙醛发生缩聚反应，生成聚硫代酰胺 。
Application
4,4′-三亚甲二哌啶用于由市售单体合成超支化共聚物：二乙烯基砜，4,4′-三亚甲基二哌啶和 N -乙二胺 。它被用于合成二维和三维镉有机骨架 。
用于合成以下物质的反应物：
- 肿瘤 pH 响应性聚合物胶束
- 缩醛改性葡聚糖微粒
- 水凝胶类
- 功能化四唑
- 抗惊厥药
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Hyperbranched copolymers made from A2, B2 and BB' 2type monomers (iv).
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Preparation of polythioamides from dialdehydes and 4, 4'-trimethylenedipiperidine with sulfur by the Willgerodt-Kindler reaction.
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Three novel cadmium-organic frameworks built-up from 1,3,5-benzenetricarboxylate anions (HXBTC(x-3)) and 4,4'-trimethylenedipyridine (TMD) have been hydrothermally synthesized, and characterized using single-crystal X-ray diffraction, thermoanalytical measurements, elemental analysis, and IR and Raman spectroscopies: [Cd(HBTC)(TMD)(2)].8.5H(2)O (I), [Cd(HBTC)(TMD)(H(2)O)].4.5H(2)O (II), and [Cd(2)(BTC)(TMD)(2)(NO(3))].3H(2)O (III), with structures
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ACS applied materials & interfaces, 10(17), 14475-14482 (2018-04-13)
Covalent organic polymers (COPs) are a promising class of cross-linked polymeric networks and porous structures composed of covalent organic molecules that attract extensive attention. Despite increasing interest in applying COPs for applications in nanomedicine, the pH-sensitive COPs that are able
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