124036
1-溴-3-氯苯
99%
别名:
1-氯-3-溴苯, 3-氯-1-溴苯, 3-溴-1-氯苯, 3-溴氯苯, m-溴氯苯
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关于此项目
线性分子式:
BrC6H4Cl
化学文摘社编号:
分子量:
191.45
NACRES:
NA.22
PubChem Substance ID:
eCl@ss:
39080308
UNSPSC Code:
12352100
EC Number:
203-575-8
MDL number:
Beilstein/REAXYS Number:
1446353
Assay:
99%
Form:
liquid
产品名称
1-溴-3-氯苯, 99%
InChI key
JRGGUPZKKTVKOV-UHFFFAOYSA-N
InChI
1S/C6H4BrCl/c7-5-2-1-3-6(8)4-5/h1-4H
SMILES string
Clc1cccc(Br)c1
assay
99%
form
liquid
refractive index
n20/D 1.576 (lit.)
bp
196 °C (lit.)
density
1.63 g/mL at 25 °C (lit.)
functional group
bromo
chloro
Quality Level
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General description
1-溴-3-氯苯与 i -PrMgCl-LiCl 在 THF 中 0°C 下发生溴-镁交换反应，并被吸电子取代基强烈加速 。它被作为测试底物，用于研究以 K 4 [Fe (CN) 6 ] 为氰基源，在各种卤代芳烃氰化反应中使用新型催化系统的应用 。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
176.0 °F - closed cup
flash_point_c
80 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
K Schümann et al.
European journal of clinical investigation, 34(4), 275-282 (2004-04-17)
Iron regulatory protein 1 (IRP1), a post-transcriptional regulator of iron metabolism, is activated in the duodenum of iron-deficient animals, which is associated with increased iron absorption. In cell cultures IRP1 was also activated by iron-independent signals, such as H(2)O(2). Here
Lei Shi et al.
The Journal of organic chemistry, 74(7), 2760-2764 (2009-03-14)
Competition experiments have been performed to determine the relative reactivities of substituted bromobenzenes, bromonaphthalenes, and 9-bromoanthracene toward i-PrMgCl x LiCl in THF at 0 degrees C. The rates of the bromine-magnesium exchange reactions are accelerated by electron-acceptor substituents, the activating
Silvina C Pérez et al.
Solid state nuclear magnetic resonance, 87, 18-23 (2017-07-01)
A simple model to explain the NQR lineshape in solids with orientational disorder or substitutional disorder is presented. The particular case of m-chlorobromobenzene is studied. It is based on the assumption that Bromine atoms, of m-chlorobromobenzene molecules, behave as point
An efficient palladium catalytic system for microwave assisted cyanation of aryl halides.
Hajipour AR, et al.
Journal of Organometallic Chemistry, 696(4), 819-824 (2011)
Nicholas C Pflug et al.
Environmental science & technology, 53(9), 4813-4822 (2019-03-27)
Anilines have been shown to be especially susceptible to single-electron oxidation by excited triplet-state photosensitizers (3sens*), and thus, are good potential candidates to probe the oxidative properties of triplet-state chromophoric dissolved organic matter (3CDOM*). However, steady-state experiments tend to underestimate
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