125504
环丙胺
98%
别名:
氨基环丙烷
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关于此项目
线性分子式:
C3H5NH2
化学文摘社编号:
分子量:
57.09
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
212-142-2
Beilstein/REAXYS Number:
741858
MDL number:
Assay:
98%
Form:
liquid
InChI key
HTJDQJBWANPRPF-UHFFFAOYSA-N
InChI
1S/C3H7N/c4-3-1-2-3/h3H,1-2,4H2
SMILES string
NC1CC1
vapor pressure
4.67 psi ( 20 °C)
assay
98%
form
liquid
autoignition temp.
527 °F
Quality Level
bp
49-50 °C (lit.)
density
0.824 g/mL at 25 °C (lit.)
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Application
环丙胺 (CPA) 用于 N -\ [4-（4-氟）苯基-2-氨基噻唑-5-基] 嘧啶-2-基-烷基胺衍生物的合成 。已用于合成 Pt (CPA) 2 （ 双甲硫亚甲基丙二酸酯）和 Pt (CPA) 2 （双 乙基硫亚甲基丙二酸酯）配合物 。
Biochem/physiol Actions
环丙胺通过一种机制使细胞色素 P450 酶失活，该机制包括在氮气中先发生单电子氧化，然后环丙烷环断裂，导致酶的共价修饰 。它是 脱氮副球菌 中一种基于机制的喹啉甲胺脱氢酶抑制剂。
signalword
Danger
存储类别
3 - Flammable liquids
wgk
WGK 2
flash_point_f
33.8 °F - closed cup
flash_point_c
1 °C - closed cup
ppe
Faceshields, Gloves, Goggles
hcodes
Hazard Classifications
Acute Tox. 4 Inhalation - Acute Tox. 4 Oral - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B
法规信息
危险化学品
此项目有
Dapeng Sun et al.
FEBS letters, 517(1-3), 172-174 (2002-06-14)
Cyclopropylamine is a mechanism-based inhibitor of the quinoprotein methylamine dehydrogenase (MADH) from Paracoccus denitrificans. The resulting inactivation is accompanied by the formation of a covalent cross-link between the alpha and beta subunits of MADH. The results of site-directed mutagenesis studies
Synthesis and Antifungal Activity of 5-[2-(Alkylamino) pyrimidin-4-yl]-4-phenylthiazol-2-cycloalkylamine Derivatives on Phytophthora capsici.
Nam Sw, et al.
J. Korean Chem. Soc., 54(3), 395-402 (2011)
David J Aitken et al.
Organic & biomolecular chemistry, 9(21), 7517-7524 (2011-09-23)
The Kulinkovich-de Meijere reaction between an unsaturated Grignard reagent and a chiral amide takes place with a high trans stereoselectivity and provides a convenient access to non-racemic trans cyclopropylamines. These compounds are transformed in four steps into the corresponding N-protected
Mark E Scott et al.
The Journal of organic chemistry, 73(21), 8154-8162 (2008-10-10)
This manuscript describes a highly selective iodide-mediated, tandem Mannich/cyclization to afford trans-2,3-disubstituted pyrrolidines from methylenecyclopropyl amides in good to excellent yields and selectivities. The reaction scope has been drastically expanded to include a wide array of aromatic, heteroaromatic and alpha,beta-unsaturated
Etienne Veignie et al.
Environmental pollution (Barking, Essex : 1987), 129(1), 1-4 (2004-01-30)
In order to study the enzymatic mechanisms involved in the successive steps of BaP degradation by a Deuteromycete fungus Fusarium solani, we developed an indirect approach by using inhibitors of enzymes. We used either specific inhibitors of peroxidases (i.e. salicylhydroxamic
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