127280
1-辛炔-3-醇
96%
别名:
(RS)-1-Octyn-3-ol, (±)-1-Octyn-3-ol, 1-Ethynyl-1-hexanol, 3-Hydroxyoct-1-yne
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关于此项目
线性分子式:
CH3(CH2)4CH(OH)C≡CH
化学文摘社编号:
分子量:
126.20
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
NACRES:
NA.22
EC Number:
212-455-4
Beilstein/REAXYS Number:
1098642
产品名称
1-辛炔-3-醇, 96%
InChI key
VUGRNZHKYVHZSN-UHFFFAOYSA-N
InChI
1S/C8H14O/c1-3-5-6-7-8(9)4-2/h2,8-9H,3,5-7H2,1H3
SMILES string
CCCCCC(O)C#C
assay
96%
form
liquid
refractive index
n20/D 1.441 (lit.)
bp
83 °C/19 mmHg (lit.)
density
0.864 g/mL at 25 °C (lit.)
Quality Level
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Application
1-Octyn-3-ol was used in the synthesis of synthetic tricolorin A, a novel tetrasaccharide macrolactone that is a natural herbicide†.
General description
1-Octyn-3-ol is a racemic intermediate formed during the synthesis of enantiomerically pure secondary alcohols with sterically similar substituents.
wgk
WGK 3
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Oral - Aquatic Acute 1
存储类别
10 - Combustible liquids
flash_point_f
145.4 °F - closed cup
flash_point_c
63 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
法规信息
新产品
此项目有
José-Luis Abad et al.
The Journal of organic chemistry, 68(13), 5351-5356 (2003-06-21)
A novel chemoenzymatic strategy for the synthesis of enantiomerically pure secondary alcohols with sterically similar substituents is described. The key step is the kinetic lipase-catalyzed resolution of racemic mixtures of substituted propargylic alcohols. The efficiency of this new approach was
Daniel P. Larson et al.
The Journal of organic chemistry, 62(24), 8406-8418 (2001-10-24)
Tricolorin A (1) is a novel tetrasaccharide macrolactone that is a natural herbicide. In this paper is reported a total synthesis of 1. Coupling of hydroxy ester 18 with D-fucosyl trichloroacetimidate 23 gave fucoside 24. Removal of the C-2 pivaloyl
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