129852
2-糠酸甲酯
98%
别名:
2-呋喃甲酸甲酯, 2-呋喃羧酸甲酯
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关于此项目
经验公式（希尔记法）:
C6H6O3
化学文摘社编号:
分子量:
126.11
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
210-254-6
Beilstein/REAXYS Number:
111110
MDL number:
产品名称
2-糠酸甲酯, 98%
Quality Level
InChI key
HDJLSECJEQSPKW-UHFFFAOYSA-N
InChI
1S/C6H6O3/c1-8-6(7)5-3-2-4-9-5/h2-4H,1H3
SMILES string
COC(=O)c1ccco1
assay
98%
form
liquid
refractive index
n20/D 1.487 (lit.)
bp
181 °C (lit.)
density
1.179 g/mL at 25 °C (lit.)
functional group
ester
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Application
2-糠酸甲酯（呋喃-2-羧酸甲酯，焦木酸甲酯）被用于合成顺式融合的5-氧呋喃[2,3-b]呋喃。它也可用于倍半萜内酯的制备。
signalword
Danger
hcodes
Hazard Classifications
Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
wgk
WGK 3
flash_point_f
163.4 °F - closed cup
flash_point_c
73 °C - closed cup
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Roland Weisser et al.
Organic letters, 7(24), 5353-5356 (2005-11-18)
[structure: see text] A short and enantioselective synthesis of cis-fused 5-oxofuro[2,3-b]furans, being found in many spongiane diterpenoid natural products, is reported starting from inexpensive methyl 2-furoate. Moreover, the acid-catalyzed rearrangement of the furo[2,3-b]furan framework A to B is observed for
Andreas Kreuzer et al.
Organic letters, 15(13), 3420-3423 (2013-06-26)
The first total synthesis of either enantiomer of Arteludovicinolide A and their biological evaluation is reported, featuring a new strategy for the asymmetric construction of γ-butyrolactones with stereogenic side chains in the 4-position. Starting from the renewable resource methyl 2-furoate
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