137685
2-溴乙基乙酸酯
97%
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线性分子式:
CH3COOCH2CH2Br
化学文摘社编号:
分子量:
167.00
UNSPSC Code:
12352100
NACRES:
NA.22
PubChem Substance ID:
EC Number:
213-159-8
Beilstein/REAXYS Number:
1743110
MDL number:
Assay:
97%
InChI
1S/C4H7BrO2/c1-4(6)7-3-2-5/h2-3H2,1H3
InChI key
RGHQKFQZGLKBCF-UHFFFAOYSA-N
SMILES string
CC(=O)OCCBr
assay
97%
impurities
<3% acetic anhydride
bp
159 °C (lit.)
mp
−14-−13.8 °C (lit.)
density
1.514 g/mL at 25 °C (lit.)
functional group
bromo, ester
Application
在不对称全合成 (+)-1-脱氧石蒜碱和 (+)-石蒜碱的过程中，采用 2-溴乙酸乙酯作为烷基化试剂 。
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 3
flash_point_f
159.8 °F - closed cup
flash_point_c
71 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Takuya Uto et al.
Physical chemistry chemical physics : PCCP, 20(31), 20669-20677 (2018-07-31)
Chitin is a promising biomass resource and has high potential for industrial applications owing to its huge annual production in nature. However, it exhibits poor processability and solubility due to its very stable and crystalline character. Recently, ionic liquids (ILs)
The first asymmetric total syntheses of (+)-lycorine and (+)-1-deoxylycorine.
Schultz AG, et al.
Journal of the American Chemical Society, 118(26), 6210-6219 (1996)
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