142514
3-溴丙酰氯
technical grade
别名:
β-溴丙酰氯, ψ-溴丙酰氯, 3-溴丙酰氯, 3-溴丙酸氯化物
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关于此项目
线性分子式:
BrCH2CH2COCl
化学文摘社编号:
分子量:
171.42
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
239-515-2
MDL number:
产品名称
3-溴丙酰氯, technical grade
InChI key
IHBVNSPHKMCPST-UHFFFAOYSA-N
InChI
1S/C3H4BrClO/c4-2-1-3(5)6/h1-2H2
SMILES string
ClC(=O)CCBr
grade
technical grade
form
liquid
refractive index
n20/D 1.49 (lit.)
bp
55-57 °C/17 mmHg (lit.)
density
1.701 g/mL at 25 °C (lit.)
functional group
acyl chloride
bromo
storage temp.
2-8°C
Quality Level
Application
3-溴丙酰氯用于制备 1-氯-4-溴-2-丁酮 。
General description
3-溴丙酰氯与聚（乙二醇）甲基丙烯酸酯反应生成溴化聚（乙二醇）甲基丙烯酸酯 。引起 4-芳基取代的 3，4-二氢嘧啶 (1 H )-2-硫酮的酰化，生成双环嘧啶并 [2，1- b ] [1，3] 噻嗪。
signalword
Danger
hcodes
Hazard Classifications
Skin Corr. 1B - STOT SE 3
target_organs
Respiratory system
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
174.2 °F - closed cup
flash_point_c
79 °C - closed cup
ppe
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Synthesis and Characterization of a Novel Macromonomer Initiator for Reversible Addition Fragmentation Chain Transfer (RAFT). Evaluation of the Polymerization Kinetics and Gelation Behaviors.
Ozturk T and Hazer B.
Journal of Macromolecular Science, Part A: Pure and Applied Chemistry, 47(3), 265-272 (2010)
Synthesis of bicyclic pyrimido [2, 1-b][1, 3] thiazines based on 3, 4-dihydropyrimidine-(1H)-2-thiones.
Kulakov IV and Turdybekov DM.
Chemistry of Heterocyclic Compounds, 46(3), 342-346 (2010)
A Nagy et al.
Proceedings of the National Academy of Sciences of the United States of America, 93(6), 2464-2469 (1996-03-19)
A convenient, high yield conversion of doxorubicin to 3'-deamino-3'-(2''-pyrroline-1''-yl)doxorubicin is described. This daunosamine-modified analog of doxorubicin is 500-1000 times more active in vitro than doxorubicin. The conversion is effected by using a 30-fold excess of 4-iodobutyraldehyde in anhydrous dimethylformamide. The
Ji Eon Chae et al.
Polymers, 13(5) (2021-03-07)
Polystyrene-based polymers with variable molecular weights are prepared by radical polymerization of styrene. Polystyrene is grafted with bromo-alkyl chains of different lengths through Friedel-Crafts acylation and quaternized to afford a series of hydroxide-ion-conducting ionomers for the catalyst binder for the
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