14664
三苯基膦，聚合物键合
100-200 mesh, extent of labeling: ~3.2 mmol/g loading
别名:
二苯基膦-聚苯乙烯, 聚苯乙烯交联二乙烯基苯，二苯基磷化, 苯乙烯-二乙烯基苯共聚物，二苯基磷化
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关于此项目
线性分子式:
-C6H4P(C6H5)2
化学文摘社编号:
分子量:
262.29
MDL编号:
UNSPSC代码:
12352128
PubChem化学物质编号:
NACRES:
NA.22
表单
solid
质量水平
反应适用性
reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reaction type: solution phase peptide synthesis
reagent type: ligand
标记范围
~3.2 mmol/g loading
基质
crosslinked with 2% DVB
粒径
100-200 mesh
官能团
phosphine
SMILES字符串
c1ccc(cc1)P(c2ccccc2)c3ccccc3
InChI
1S/C18H15P/c1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18/h1-15H
InChI key
RIOQSEWOXXDEQQ-UHFFFAOYSA-N
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应用
Polymer-bound triphenylphosphine (PPh3) is a reusable organocatalyst for the Mukaiyama aldol and Mannich reaction. It can also be used as a traceless reagent for Mitsunobu reaction in combinatorial chemistry to synthesize aryl ethers from phenols and alcohols.
储存分类代码
11 - Combustible Solids
WGK
WGK 3
个人防护装备
dust mask type N95 (US), Eyeshields, Faceshields, Gloves
Polymer-supported PPh 3 as a reusable organocatalyst for the Mukaiyama aldol and Mannich reaction.
Matsukawa S, et al.
Royal Society of Chemistry Advances, 4(53), 27780-27786 (2014)
Polymer-bound triphenylphosphine as traceless reagent for Mitsunobu reactions in combinatorial chemistry: Synthesis of aryl ethers from phenols and alcohols.
Tunoori A R, et al.
Tetrahedron Letters, 39(48), 8751-8754 (1998)
Uday Narayan Maiti et al.
ACS applied materials & interfaces, 7(46), 25898-25905 (2015-11-03)
A scalable and controllable nanoscale perforation method for graphene is developed on the basis of the two-step thermal activation of a graphene aerogel. Different resistance to the thermal oxidation between graphitic and defective domains in the weakly reduced graphene oxide
Hui Yang et al.
Toxicology letters, 230(1), 10-18 (2014-08-08)
Gold nanoparticles (GNPs) have considerable applications in biomedicine, such as in bio-sensing, bio-imaging, drug delivery and photothermal therapeutics. However, currently there are limited information regarding the impact of pregnancy on their biodistribution, elimination and toxicity. In this study, we investigated
Crispin Lichtenberg et al.
Dalton transactions (Cambridge, England : 2003), 44(46), 20056-20066 (2015-11-04)
A diolefin ether, trop2O (2), and a diolefin thioether, trop2S (3), have been investigated as ligand analogues of the well-established diolefin amine, trop2NH (1). Compounds 2 and 3 form different conformers in solution and in the solid state. Whereas 2
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