14827
(S)-(-)-N,N-双(2-二苯基膦乙基)-1-苯乙胺
≥98.0% (CHN)
别名:
(S)-(-)-N,N-双(2-二苯基膦乙基)-α-甲基苄胺
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关于此项目
经验公式（希尔记法）:
C36H37NP2
化学文摘社编号:
分子量:
545.63
UNSPSC Code:
12352116
NACRES:
NA.22
PubChem Substance ID:
MDL number:
Beilstein/REAXYS Number:
4608384
InChI
1S/C36H37NP2/c1-31(32-17-7-2-8-18-32)37(27-29-38(33-19-9-3-10-20-33)34-21-11-4-12-22-34)28-30-39(35-23-13-5-14-24-35)36-25-15-6-16-26-36/h2-26,31H,27-30H2,1H3/t31-/m0/s1
SMILES string
C[C@H](N(CCP(c1ccccc1)c2ccccc2)CCP(c3ccccc3)c4ccccc4)c5ccccc5
InChI key
ZVNAHLJBPYKGBV-HKBQPEDESA-N
assay
≥98.0% (CHN)
form
solid
optical activity
[α]20/D −4.5±0.7°, c = 1% in acetone
General description
(S)-(−)-N,N-Bis(2-diphenylphosphinoethyl)-1-phenylethylamine is a chiral ligand used to prepare its iridium complexes, applicable in the synthesis of allylic alcohols via reduction of α,β-unsaturated ketones.
signalword
Danger
hcodes
Hazard Classifications
Eye Dam. 1 - Skin Corr. 1B
存储类别
8A - Combustible corrosive hazardous materials
wgk
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
法规信息
新产品
此项目有
Synthesis of the New Chiral Aminodiphosphine Ligands (R)-and (S)-(alpha-Methylbenzyl) bis (2-(diphenylphosphino) ethyl) amine and Their Use in the Enantioselective Reduction of α, β-Unsaturated Ketones to Allylic Alcohols by Iridium Catalysis
Bianchini C, et al.
Organometallics, 14(3), 1489-1502 (1995)
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