15145
(-)-双[(S)-1-苯基乙基]胺 盐酸盐
≥98.0% (AT)
别名:
(-)-双[(S)-α-甲苄基]胺 盐酸盐
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关于此项目
经验公式（希尔记法）:
C16H19N · HCl
CAS Number:
分子量:
261.79
Beilstein:
4723969
MDL编号:
UNSPSC代码:
12352116
PubChem化学物质编号:
NACRES:
NA.22
方案
≥98.0% (AT)
表单
solid
旋光性
[α]20/D −73±2°, c = 3% in ethanol
mp
~260 °C
SMILES字符串
Cl.C[C@H](N[C@@H](C)c1ccccc1)c2ccccc2
InChI
1S/C16H19N.ClH/c1-13(15-9-5-3-6-10-15)17-14(2)16-11-7-4-8-12-16;/h3-14,17H,1-2H3;1H/t13-,14-;/m0./s1
InChI key
ZBQCLJZOKDRAOW-IODNYQNNSA-N
应用
(−)-Bis[(S)-1-phenylethyl]amine hydrochloride can be used:
- To prepare phosphoramidite (Feringa) ligand named (R)-2,2′-binaphthoyl-(S,S)-di-(1-phenylethyl)aminoylphosphine.
- As a chiral amphiphilic cation to encapsulate polyoxometalates, which act as supramolecular assemblies employed in the asymmetric oxidation of sulfides.
- As a chiral shift agent in the determination of enantiomeric purity of tris(tetrachlorobenzenediolato) phosphate(V) anion using 31P NMR.
其他说明
对应的手性氨基化锂可作为碱，用于酮的对映选择性脱质子化反应。
警示用语：
Warning
危险声明
危险分类
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
靶器官
Respiratory system
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
dust mask type N95 (US), Eyeshields, Gloves
Supramolecular assembly of chiral polyoxometalate complexes for asymmetric catalytic oxidation of thioethers
Wang Y, et al.
Journal of Materials Chemistry, 22(18), 9181-9188 (2012)
Large-scale synthesis and resolution of trisphat [tris (tetrachlorobenzenediolato) phosphate (v)] anion
Favarger F, et al.
The Journal of Organic Chemistry, 69(24), 8521-8524 (2004)
P.J. Cox et al.
Tetrahedron Asymmetry, 2, 1-1 (1991)
(R)-2, 2′-Binaphthoyl-(S, S)-DI (1-phenylethyl) aminophosphine. Scalable protocols for the syntheses of phosphoramidite (feringa) ligands
Smith CR, et al.
Organic Syntheses, 85, 238-238 (2008)
M. Majewski et al.
The Journal of Organic Chemistry, 57, 3599-3599 (1992)
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