15587
硼烷二甲基硫醚络合物
technical, >90% in dimethyl sulfide
别名:
硼烷二甲硫醚, 硼烷甲基硫醚络合物
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关于此项目
线性分子式:
(CH3)2S · BH3
化学文摘社编号:
分子量:
75.97
PubChem Substance ID:
UNSPSC Code:
12352000
MDL number:
Beilstein/REAXYS Number:
3663489
SMILES string
B.CSC
grade
technical
reaction suitability
reagent type: reductant
concentration
>90% in dimethyl sulfide
density
0.801 g/mL at 20 °C (lit.)
storage temp.
2-8°C
Application
Reactant used as a regioselective reducing agent
Reactant involved in:
Reactant involved in:
- Hydroboration / oxidation
- Synthesis of cage compounds
Other Notes
方便而稳定的硼烷来源，用于硼氢化反应，综述；α-羟基酯的选择性还原反应
signalword
Danger
supp_hazards
存储类别
4.3 - Hazardous materials which set free flammable gases upon contact with water
wgk
WGK 1
flash_point_f
64.4 °F
flash_point_c
18 °C
ppe
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Hazard Classifications
Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Repr. 1B - Water-react. 1
法规信息
新产品
此项目有
H.C. Brown et al.
The Journal of Organic Chemistry, 47, 3153-3153 (1982)
S. Saito et al.
Chemistry Letters (Jpn), 1389-1389 (1984)
R.O. Hutchins et al.
Organic preparations and procedures international, 13, 225-225 (1981)
S. Krishnamurthy
Tetrahedron Letters, 23, 3315-3315 (1982)
Isidoro González-Álvaro et al.
Rheumatology (Oxford, England), 54(7), 1200-1209 (2014-12-21)
The aim of this study was to establish guidelines for the optimization of biologic therapies for health professionals involved in the management of patients with RA, AS and PsA. Recommendations were established via consensus by a panel of experts in
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