155888
反式-2-甲基-3-苯基-2-丙烯-1-醇
95%
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关于此项目
线性分子式:
C6H5CH=C(CH3)CH2OH
化学文摘社编号:
分子量:
148.20
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
EC Number:
216-128-7
MDL number:
Assay:
95%
Form:
liquid
InChI key
LLNAMUJRIZIXHF-VQHVLOKHSA-N
InChI
1S/C10H12O/c1-9(8-11)7-10-5-3-2-4-6-10/h2-7,11H,8H2,1H3/b9-7+
SMILES string
[H]\C(=C(\C)CO)c1ccccc1
assay
95%
form
liquid
refractive index
n20/D 1.572 (lit.)
bp
77 °C/0.1 mmHg (lit.)
density
1.03 g/mL at 25 °C (lit.)
functional group
hydroxyl, phenyl
Application
trans-2-Methyl-3-phenyl-2-propen-1-ol was used in the preparation of 5-methyl-4-phenyl-5-hexen-2-one.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
10 - Combustible liquids
wgk
WGK 2
flash_point_f
235.4 °F - closed cup
flash_point_c
113 °C - closed cup
ppe
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
L Angermaier et al.
Hoppe-Seyler's Zeitschrift fur physiologische Chemie, 362(1), 33-38 (1981-01-01)
With ethanol as electron donor, resting cells of Clostridium kluyveri reduced (E)-2-methyl-2-buten-1-ol, (E)-3-methyl-2-penten-1-ol and (E)-2-methyl-3-phenyl-2-propen-1-ol to (R)-2-methyl-1-butanol, (R)-3-methyl-1-1-pentanol and (R)-2-methyl-3-phenyl-1-propanol, respectively. Within the experimental errors of ORD measurements the products were optically pure. That means that only one of the
Masao Morita et al.
The Journal of organic chemistry, 71(16), 6285-6286 (2006-07-29)
One-pot synthesis of gamma,delta-unsaturated carbonyl compounds from allyl alcohols and vinyl or isopropenyl acetates was achieved through in situ generation of allyl vinyl ethers by the action of the [IrCl(cod)]2 complex followed by Claisen rearrangement of the resulting ethers. For
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