156744
1-氯异喹啉
95%
登录 查看组织和合同定价。
选择尺寸
变更视图
关于此项目
经验公式（希尔记法）:
C9H6ClN
化学文摘社编号:
分子量:
163.60
NACRES:
NA.22
PubChem Substance ID:
UNSPSC Code:
12352100
MDL number:
Assay:
95%
Quality Level
assay
95%
bp
274-275 °C/768 mmHg (lit.)
mp
31-36 °C (lit.)
functional group
chloro
SMILES string
Clc1nccc2ccccc12
InChI
1S/C9H6ClN/c10-9-8-4-2-1-3-7(8)5-6-11-9/h1-6H
InChI key
MSQCQINLJMEVNJ-UHFFFAOYSA-N
Application
The product has been used in a Mn-catalyzed cross-coupling with aryl- and alkylmagnesium halides. It has also been used in a Pd-catalyzed cross-coupling with heteroaryl boronic acids and esters. Furthermore, it has been used in a homocoupling reaction to yield bis-isoquinoline, each enantiomer of which might be very useful as a chiral ligand for asymmetric synthesis.
signalword
Warning
hcodes
Hazard Classifications
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
target_organs
Respiratory system
存储类别
11 - Combustible Solids
ppe
dust mask type N95 (US), Eyeshields, Gloves
Synlett, 247-247 (2007)
Homocoupling of aryl iodides and bromides using a palladium/indium bimetallic system.
Chang, Yu Mi, et al.
Synthetic Communications, 35(13), 1851-1857 (2005)
Kelvin Billingsley et al.
Journal of the American Chemical Society, 129(11), 3358-3366 (2007-03-01)
A highly active and efficient catalyst system derived from a palladium precatalyst and monophosphine ligands 1 or 2 for the Suzuki-Miyaura cross-coupling reaction of heteroaryl boronic acids and esters has been developed. This method allows for the preparation of a
全球贸易项目编号
| 货号 | GTIN |
|---|---|
| 156744-1G | 04061838742872 |
| 156744-5G | 04061832977324 |