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156876

N-羟乙基苯胺

Name: <I>N</I>-羟乙基苯胺
Brand: ALDRICH

98%

别名:

2-苯氨基乙醇, 2-苯胺乙醇, N-苯基乙醇胺

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关于此项目

线性分子式:

C₆H₅NHCH₂CH₂OH

化学文摘社编号:

122-98-5

分子量:

137.18

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24849642

MDL number:

MFCD00002832

Beilstein/REAXYS Number:

774672

Assay:

98%

Form:

liquid

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属性

vapor density

>1 (vs air)

Quality Level

200

vapor pressure

<0.01 mmHg ( 20 °C)

assay

98%

form

liquid

refractive index

n20/D 1.578 (lit.)

bp

278-282 °C/760 mmHg (lit.)

density

1.094 g/mL at 25 °C (lit.)

SMILES string

OCCNc1ccccc1

InChI

1S/C8H11NO/c10-7-6-9-8-4-2-1-3-5-8/h1-5,9-10H,6-7H2

InChI key

MWGATWIBSKHFMR-UHFFFAOYSA-N

说明

Application

N-（2-羟乙基）苯胺被用作人嗅觉UDP-葡糖醛酸糖基转移酶的底物。

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pictograms

GHS06,GHS08,GHS05,GHS09

signalword

Danger

hcodes

H301,H310,H318,H370,H373,H411

pcodes

P262 - P273 - P280 - P301 + P310 - P302 + P352 + P310 - P305 + P351 + P338

Hazard Classifications

Acute Tox. 2 Dermal - Acute Tox. 3 Oral - Aquatic Chronic 2 - Eye Dam. 1 - STOT RE 2 - STOT SE 1

target_organs

Blood, Blood,hematopoietic system

存储类别

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Straightforward stereoselective access to cyclic peptidomimetics.

Santos Fustero et al.

The Journal of organic chemistry, 74(11), 4429-4432 (2009-05-15)

The preparation of cyclic dipeptide mimetics from chiral imino lactones derived from (R)-phenylglycinol is described. Key steps of the synthetic route included the fully stereoselective construction of a quaternary center, the formation of six-, seven-, or eight-membered lactams by means

Diastereoselective protonation of lactam enolates derived from (R)-phenylglycinol. A novel asymmetric route to 4-phenyl-1,2,3, 4-tetrahydroisoquinolines.

N Philippe et al.

Organic letters, 2(15), 2185-2187 (2000-08-10)

Highly diastereoselective protonation of chiral lactam enolates of 4-substituted-1,4-dihydroisoquinolin-3-ones is reported. Protonation and alkylation processes of these lactam enolates derived from phenylglycinol occur with opposite diastereofacial selectivity. This diastereoselective protonation has been applied to the asymmetric synthesis of (4S)-N-methyl-4-phenyl-1,2,3,4-tetrahydroisoquinoline 9

Dynamic kinetic resolution and desymmetrization processes: a straightforward methodology for the enantioselective synthesis of piperidines.

Mercedes Amat et al.

Chemistry (Weinheim an der Bergstrasse, Germany), 12(30), 7872-7881 (2006-07-20)

A straightforward procedure for the synthesis of enantiopure polysubstituted piperidines is reported. It involves the direct generation of chiral non-racemic oxazolo[3,2-a]piperidone lactams that already incorporate carbon substituents on the heterocyclic ring and the subsequent removal of the chiral auxiliary. The

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