157457
3,5-二叔丁基邻苯醌
98%
别名:
3,5-二叔丁基-1,2-苯醌, 3,5-二叔丁基-o-苯醌, 3,5-二叔丁基环己基-3,5-二烯-1,2-二酮, 3,5-二叔丁基苯醌, 3,5-双(1,1-二甲基乙基)-3,5-环己二烯-1,2-二酮, 4,6-二叔丁基-1,2-苯醌, 4,6-二叔丁基-o-苯醌
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关于此项目
线性分子式:
[(CH3)3C]2C6H2(=O)2
化学文摘社编号:
分子量:
220.31
Beilstein:
2047944
EC 号:
MDL编号:
UNSPSC代码:
12352100
PubChem化学物质编号:
NACRES:
NA.22
质量水平
方案
98%
表单
solid
mp
112-114 °C (lit.)
SMILES字符串
CC(C)(C)C1=CC(=O)C(=O)C(=C1)C(C)(C)C
InChI
1S/C14H20O2/c1-13(2,3)9-7-10(14(4,5)6)12(16)11(15)8-9/h7-8H,1-6H3
InChI key
NOUZOVBGCDDMSX-UHFFFAOYSA-N
基因信息
human ... ACHE(43), BCHE(590), CES1(1066)
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一般描述
次膦基桥联络合物[[Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph) 与3,5-二-叔-丁基-o-苯醌的反应已有报道。
应用
3,5-二-叔-丁基-o-苯醌可用于制备苯并恶唑衍生物配体。其可与无环二烯发生杂原子Diels Alder反应，制备1,4-苯二恶英。
储存分类代码
11 - Combustible Solids
WGK
WGK 3
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves, type N95 (US)
Akira Kotani et al.
Analytical sciences : the international journal of the Japan Society for Analytical Chemistry, 19(11), 1473-1476 (2003-12-03)
A disposable voltammetric cell using three pencil leads as working, reference, and counter electrodes was developed for determining the titratable acidity, i.e. the acid content in vinegar. The materials of the pencil leads were graphite-reinforcement carbons (GRCs). A voltammetric determination
Olga Iasco et al.
Inorganic chemistry, 51(4), 2588-2596 (2012-01-12)
Two benzoxazoles derivative ligands were synthesized from the condensation of 3,5-di-tert-butyl-o-benzoquinone (DTBBQ) with ethanolamine or 1,3-diamino-2-hydroxypropane in methanol. Condensation of DTBBQ with ethanolamine gives the expected 5,7-di-tert-butyl-2-methylenhydroxylbenzoxazole (HL1) while with 1,3-diamino-2-hydroxypropane it gives (2-hydroxyethyl-2-{2,4-bis(1,1-dimethylethyl)-1-phenol-6 amino}-2{5,7-di-tert-butyl-benzoxazole}) (H(2)L2) with only one benzoxazole
Chinmoy Das et al.
Dalton transactions (Cambridge, England : 2003), 46(5), 1439-1448 (2017-01-11)
The reaction of anhydrous MCl
Norma A Macías-Ruvalcaba et al.
The journal of physical chemistry. B, 110(43), 22043-22047 (2006-10-27)
The electrochemical reduction of 3,5-di-tert-butyl-1,2-benzoquinone, 1, has been studied in acetonitrile with added 2,2,2-trifluoroethanol, 2. At low concentrations of 2 the reaction proceeds by the following pathway: reduction of the quinone (Q) to its anion radical (Q*-) followed by complexation
M Angeles Alvarez et al.
Dalton transactions (Cambridge, England : 2003), 41(48), 14498-14513 (2012-10-12)
The title complexes reacted readily with the methylating agents MeI and CF(3)SO(3)Me, chalcogens (O(2), S(8)) and borane adducts BH(3)·L (L = THF, N(t)Bu(3), PPh(3)) to initially give the corresponding neutral or cationic derivatives of the type [Fe(2)Cp(2){μ-P(E)R}(μ-CO)(CO)(2)](n) (Cp = η(5)-C(5)H(5);
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