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157457

3,5-二叔丁基邻苯醌

Name: 3,5-二叔丁基邻苯醌
Brand: ALDRICH

98%

别名:

3,5-二叔丁基-1,2-苯醌, 3,5-二叔丁基-o-苯醌, 3,5-二叔丁基环己基-3,5-二烯-1,2-二酮, 3,5-二叔丁基苯醌, 3,5-双(1,1-二甲基乙基)-3,5-环己二烯-1,2-二酮, 4,6-二叔丁基-1,2-苯醌, 4,6-二叔丁基-o-苯醌

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关于此项目

线性分子式:

[(CH₃)₃C]₂C₆H₂(=O)₂

化学文摘社编号:

3383-21-9

分子量:

220.31

UNSPSC Code:

12352100

NACRES:

NA.22

PubChem Substance ID:

24849680

EC Number:

222-189-0

Beilstein/REAXYS Number:

2047944

MDL number:

MFCD00001647

Assay:

98%

Form:

solid

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属性

Quality Level

100

assay

98%

form

solid

mp

112-114 °C (lit.)

SMILES string

CC(C)(C)C1=CC(=O)C(=O)C(=C1)C(C)(C)C

InChI

1S/C14H20O2/c1-13(2,3)9-7-10(14(4,5)6)12(16)11(15)8-9/h7-8H,1-6H3

InChI key

NOUZOVBGCDDMSX-UHFFFAOYSA-N

Gene Information

human ... ACHE(43), BCHE(590), CES1(1066)

说明

General description

次膦基桥联络合物[[Fe₂(η⁵-C₅H₅)₂(μ-PR)(μ-CO)(CO)₂] (R = Cy, Ph) 与3,5-二-叔-丁基-o-苯醌的反应已有报道。

Application

3,5-二-叔-丁基-o-苯醌可用于制备苯并恶唑衍生物配体。其可与无环二烯发生杂原子Diels Alder反应，制备1,4-苯二恶英。

存储类别

11 - Combustible Solids

wgk

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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The Pro-Oxidant Activity of Pheomelanin is Significantly Enhanced by UVA Irradiation: Benzothiazole Moieties Are More Reactive than Benzothiazine Moieties.

Hitomi Tanaka et al.

International journal of molecular sciences, 19(10) (2018-09-27)

It is generally considered that eumelanin (EM) is photoprotective while pheomelanin (PM) is phototoxic. A recent study using a mouse model demonstrated that PM produces reactive oxygen species (ROS) that cause DNA damage and eventually lead to melanomagenesis. A biochemical

Reactions of the phosphinidene-bridged complexes [Fe2(η5-C5H5)2(μ-PR)(μ-CO)(CO)2] (R = Cy, Ph) with electrophiles based on p-block elements.

M Angeles Alvarez et al.

Dalton transactions (Cambridge, England : 2003), 41(48), 14498-14513 (2012-10-12)

The title complexes reacted readily with the methylating agents MeI and CF(3)SO(3)Me, chalcogens (O(2), S(8)) and borane adducts BH(3)·L (L = THF, N(t)Bu(3), PPh(3)) to initially give the corresponding neutral or cationic derivatives of the type [Fe(2)Cp(2){μ-P(E)R}(μ-CO)(CO)(2)](n) (Cp = η(5)-C(5)H(5);

Change in reaction pathway in the reduction of 3,5-di-tert-butyl-1,2-benzoquinone with increasing concentrations of 2,2,2-trifluoroethanol.

Norma A Macías-Ruvalcaba et al.

The journal of physical chemistry. B, 110(43), 22043-22047 (2006-10-27)

The electrochemical reduction of 3,5-di-tert-butyl-1,2-benzoquinone, 1, has been studied in acetonitrile with added 2,2,2-trifluoroethanol, 2. At low concentrations of 2 the reaction proceeds by the following pathway: reduction of the quinone (Q) to its anion radical (Q*-) followed by complexation

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货号	GTIN
157457-10G	04061838743374